The complex(es), which can exhibit the type of isomerism shown by $\left[\mathrm{Pt}{\left({\mathrm{NH}}_3\right)}_2{\mathrm{Br}}_2\right]$, is(are) $\left[\mathrm{en}={\mathrm{H}}_2{\mathrm{NCH}}_2{\mathrm{CH}}_2{\mathrm{NH}}_2\right]$

The correct option(s) to distinguish nitrate salts of $M{n}^{2+} \mathrm{a}\mathrm{n}\mathrm{d} C{u}^{2+}$ taken separately is(are)

The treatment of an aqueous solution of 3.74 g of \(\text{Cu} \left(\text{NO} _3\right)_2\) with excess KI results in a brown solution along with the formation of a precipitate. Passing \(\text{H} _2 \text{S}\) through this brown solution gives another precipitate X . The amount of X (in g ) is _____________ [Given: Atomic mass of \(\text{H} =1, \text{N}=14, \text{O} =16, \text{S}=32, \text{K}=39,\) \(\text{Cu} =63, \text{I} =127]\)

Statement I Boron always forms covalent bond
Statement II The small size of \(\mathrm{B}^{3+}\) favours formation of covalent bond.

An organic compound \(\mathbf{P}\) having molecular formula \(\mathrm{C}_6 \mathrm{H}_6 \mathrm{O}_3\) gives ferric chloride test and does not have intramolecular hydrogen bond. The compound \(\mathbf{P}\) reacts with 3 equivalents of \(\mathrm{NH}_2 \mathrm{OH}\) to produce oxime \(\mathbf{Q}\). Treatment of \(\mathbf{P}\) with excess methyl iodide in the presence of \(\mathrm{KOH}\) produces compound \(\mathbf{R}\) as the major product. Reaction of \(\mathbf{R}\) with excess iso-butylmagnesium bromide followed by treatment with \(\mathrm{H}_3 \mathrm{O}^{+}\)gives compound \(\mathrm{S}\) as the major product.
The total number of methyl \(\left(-\mathrm{CH}_3\right)\) group(s) in compound \(\mathbf{S}\) is ________. (consider maximum value if there are two values)

In dilute aqueous ${\mathrm{H}}_2\mathrm{S}{\mathrm{O}}_4$ , the complex diaquodioxalatoferrate (II) is oxidized by ${\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}$ . For this reaction, the ratio of the rate of change of $\left[{\mathrm{H}}^{+}\right]$ to the rate of change of $\left[{\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}\right]$ is

The compound(s) which react(s) with ${\mathrm{NH}}_3$ to give boron nitride $\left(\mathrm{BN}\right)$ is(are)

Upon treatment with ammoniacal ${\text{H}}_2\text{S}$, the metal ion that precipitates as a sulphide is

List I describes thermodynamic processes in four different systems. List II gives the magnitudes (either exactly or as a close approximation) of possible changes in the internal energy of the system due to the process.

	List-I		List-II
(I)	${10}^{-3} \mathrm{kg}$ of water $100 °\mathrm{C}$ is converted to steam at the same temperature, at a pressure of ${10}^5\mathrm{Pa}$. The volume of the system changes from ${10}^{-6}{\mathrm{m}}^3$ to ${10}^{-3}{\mathrm{m}}^3$ in the process. Latent heat of water $=2250 \mathrm{kJ} {\mathrm{kg}}^{-1}$	(P)	$2 \mathrm{kJ}$
(II)	$0.2$ moles of a rigid diatomic ideal gas with volume $V$ at temperature $500 \mathrm{K}$ undergoes an isobaric expansion to volume $3 V$. Assume $8.0 \mathrm{J} {\mathrm{mol}}^{–1} {\mathrm{K}}^{–1}$	(Q)	$7 \mathrm{kJ}$
(III)	One mole of a monoatomic ideal gas is compressed adiabatically from volume $V=\frac{1}{3}{\mathrm{m}}^3$ and pressure $2 \mathrm{kPa}$ to volume $\frac{V}{8}$.	(R)	$4 \mathrm{kJ}$
(IV)	Three moles of a diatomic ideal gas whose molecules can vibrate, is given $9 \mathrm{kJ}$ of heat and undergoes isobaric expansion.	(S)	$5 \mathrm{kJ}$
		(T)	$3 \mathrm{kJ}$

Which one of the following options is correct?

In the following reactions, $\mathbf{P},\mathbf{Q},\mathbf{R}$, and $\mathbf{S}$ are the major products.




The correct statement(s) about $\mathbf{P},\mathbf{Q},\mathbf{R}$, and $\mathbf{S}$ is(are)

Two balls, having linear momenta \(\overrightarrow{\mathbf{p}}_1=p \hat{\mathbf{i}}\) and \(\overrightarrow{\mathbf{p}}_2=-p \hat{\mathbf{i}}\), undergo a collision in free space. There is no external force acting on the balls. Let \(\overrightarrow{\mathbf{p}}_1^{\prime}\) and \(\overrightarrow{\mathbf{p}}_2^{\prime}\) be their final momenta. The following option(s) is/are NOT ALLOWED for any non-zero value of \(p, a_1, a_2, b_1, b_2, c_1\) and \(c_2\)

One mole of a monoatomic ideal gas goes through a thermodynamic cycle, as shown in the volume versus temperature $\left(\mathrm{V}-\mathrm{T}\right)$ diagram. The correct statement(s) is/are:
[ $\mathrm{R}$ is the gas constant]

Paragraph :
A wooden cylinder of diameter \(4 r\), height \(H\) and density \(\rho / 3\) is kept on a hole of diameter \(2 r\) of a tank, filled with liquid of density \(\rho\) as shown in the figure.

Question :
The block in the above question is maintained at the position by external means and the level of liquid is lowered. The height \(h_2\) when this external force reduces to zero is