The treatment of an aqueous solution of 3.74 g of \(\text{Cu} \left(\text{NO} _3\right)_2\) with excess KI results in a brown solution along with the formation of a precipitate. Passing \(\text{H} _2 \text{S}\) through this brown solution gives another precipitate X . The amount of X (in g ) is _____________ [Given: Atomic mass of \(\text{H} =1, \text{N}=14, \text{O} =16, \text{S}=32, \text{K}=39,\) \(\text{Cu} =63, \text{I} =127]\)

The molar conductivity of a solution of a weak acid HX (0.01 M) is 10 times smaller than the molar conductivity of a solution of a weak acid HY (0.10 M). If ${\mathrm{\lambda }}_{{\mathrm{X}}^{-}}^0\approx {\mathrm{\lambda }}_{{\mathrm{Y}}^{-}}^0$ , the difference in their $\mathrm{p}{\mathrm{K}}_{\mathrm{a}}$ values, $\mathrm{p}{\mathrm{K}}_{\mathrm{a}}\left(\mathrm{H}\mathrm{X}\right)-\mathrm{p}{\mathrm{K}}_{\mathrm{a}}\left(\mathrm{H}\mathrm{Y}\right)$ , is (Consider degree of ionization of both acids to << 1)

For the first order reaction \(2 \mathrm{~N}_2 \mathrm{O}_5(\mathrm{~g}) \longrightarrow 4 \mathrm{NO}_2(g)+\mathrm{O}_2(g)\)

The standard enthalpies of formation of $C{O}_2\left(g\right)$ ${\text{, H}}_2\text{O}\left(\mathit{\text{l}}\right)$ and glucose (s) at $25^{\text{o}}C$ are $-\text{400 kJ}/\text{mol}$, $-\text{300 kJ}/\text{mol}$ and $-\text{1300 kJ}/\text{mol}$, respectively. The standard enthalpy combustion per gram of glucose at $25^{\text{o}}C$ is $\left(\Delta H_f^0=-1300kJmo{l}^{-}for\text{glucose}\right)$

Paragraph:
An aqueous solution of a mixture of two inorganic salts, when treated with dilute \(H C\) ?, gave a precipitate \((\boldsymbol{P})\) and a filtrate \((\boldsymbol{Q})\). The precipitate \(\boldsymbol{P}\) was found to dissolve in hot water. The filtrate \((\boldsymbol{Q})\) remained unchanged, when treated with \(\mathrm{H}_{2} \mathrm{~S}\) in a dilute mineral acid medium. However, it gave a precipitate \((\boldsymbol{R})\) with \(H_{2} S\) in an ammoniacal medium. The precipitate \(\boldsymbol{R}\) gave a coloured solution \((\boldsymbol{S})\), when treated with \(\mathrm{H}_{2} \mathrm{O}_{2}\) in an aqueous \(\mathrm{NaOH}\) medium.

Question:
The precipitate \(\boldsymbol{P}\) contains

A colorless aqueous solution contains nitrates of two metals, $\mathrm{X}$ and $\mathrm{Y}$. When it was added to an aqueous solution of $\mathrm{NaCl}$, a white precipitate was formed. This precipitate was found to be partly soluble in hot water to give a residue $\mathrm{P}$ and a solution $\mathrm{Q}$. The residue $\mathrm{P}$ was soluble in aq. ${\mathrm{NH}}_3$ and also in excess sodium thiosulfate. The hot solution $\mathrm{Q}$ gave a yellow precipitate with $\mathrm{KI}$. The metals $\mathrm{X}$ and $\mathrm{Y}$, respectively, are

Statement I p-hydroxybenzoic acid has a lower boiling point than o-hydroxybenzoic acid.
Statement II o-hydroxybenzoic acid has intramolecular hydrogen bonding.

The sum of the spin only magnetic moment values (in B.M.) of \(\left[\mathrm{Mn}(\mathrm{Br})_6\right]^{3-}\) and \(\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}\) is _____.

A mixture of 2 moles of helium gas (atomic mass \(=4 \mathrm{amu}\) ) and 1 mole of argon gas (atomic mass \(=40 \mathrm{amu}\) ) is kept at \(300 \mathrm{~K}\) in a container. The ratio of the rms speeds \(\left(\frac{v_{\mathrm{rms}}(\text { helium })}{v_{\mathrm{rms}}(\operatorname{argon})}\right)\) is

The value of the limit $\underset{x\to \frac{\pi }{2}}{\lim }\frac{4\sqrt{2}\left(\sin 3x+\sin x\right)}{\left(2\sin 2x\sin \frac{3x}{2}+\cos \frac{5x}{2}\right)-\left(\sqrt{2}+\sqrt{2}\cos 2x+\cos \frac{3x}{2}\right)}$ is _________

Consider an elliptically shaped rail PQ in the vertical plane with $\mathrm{O}\mathrm{P}\mathrm{}=\mathrm{}3\mathrm{}\mathrm{m}$ and $\mathrm{O}\mathrm{Q}\mathrm{}=\mathrm{}4\mathrm{}\mathrm{m}$ . A block of mass 1 kg is pulled along the rail from P to Q with a force of 18 N, which is always parallel to line PQ (see the figure given). Assuming no frictional losses, the kinetic energy of the block when it reaches Q is $(\mathrm{n}\times 10)$ Joules. The value of n is (take acceleration due to gravity = $10\mathrm{}\mathrm{m}{\mathrm{s}}^{–2}$ )

The value of  $cot \left(\underset{\text{n}=1}{\overset{23}{\Sigma }}{\text{cot}}^{-1}\left(1+\underset{\text{k}=1}{\overset{\text{n}}{\Sigma }}2\text{k}\right)\right)$  is

Consider a branch of the hyperbola \(x^2-2 y^2-2 \sqrt{2} x-4 \sqrt{2} y-6=0\) with vertex at the point \(A\). Let \(B\) be one of the end points of its latus rectum. If \(C\) is the focus of the hyperbola nearest to the point \(A\), then the area of the \(\triangle A B C\) is