In dilute aqueous ${\mathrm{H}}_2\mathrm{S}{\mathrm{O}}_4$ , the complex diaquodioxalatoferrate (II) is oxidized by ${\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}$ . For this reaction, the ratio of the rate of change of $\left[{\mathrm{H}}^{+}\right]$ to the rate of change of $\left[{\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}\right]$ is

Match the reactions in Column I with appropriate types of steps/reactive intermediate involved in these reactions as given in Column II.

In an electrochemicalcell, dichromate ions in aqueous acidic medium are reduced to \(\mathrm{Cr}^{3+}\). The current (in amperes) that flows through the cell for 48.25 minutes to produce 1 mole of \(\mathrm{Cr}^{3+}\) is _____ .
Use: 1 Faraday \(=96500 \mathrm{C} \mathrm{mol}^{-1}\)

The complex showing a spin-only magnetic moment of \(2.82\) B.M. is

In the given reaction scheme, $\mathbf{P}$ is a phenyl alkyl ether, $\mathbf{Q}$  is an aromatic compound; $\mathbf{R}$ and $\mathbf{S}$ are the major products.

The correct statement about $\mathbf{S}$ is

The electrochemical cell shown below is a concentration cell. \(\mathrm{M} \mid \mathrm{M}^{2+}\) (saturated solution of a sparingly soluble salt, \(\left.\mathrm{MX}_{2}\right) \| \mathrm{M}^{2 \perp}\left(0.001 \mathrm{~mol} \mathrm{dm}^{-3}\right) \mid \mathrm{M}\).
The emf of the cell depends on the difference in concentrations of \(\mathrm{M}^{2+}\) ions at the two electrodes. The emf of the cell at \(298 \mathrm{~K}\) is \(0.059 \mathrm{~V}\).
Question:
The value of \(\Delta \mathrm{G}\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)\) for the given cell is (take 1 \(\mathrm{F}=96500 \mathrm{Cmol}^{-1}\) )

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Reimer-Tiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicylaldehydes as depicted below.

Question :
The electrophile in this reaction is

Let a, b, c be positive integers such that $\frac{b}{a}$ is an integer. If a, b, c are in geometric progression and the arithmetic mean of a, b, c is b + 2, then the value of $\frac{a^2+a-14}{a+1}$ is ________

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A thermally insulating cylinder has a thermally insulating and frictionless movable partition in the middle, as shown in the figure below. On each side of the partition, there is one mole of an ideal gas, with specific heat at constant volume, \(C_{V}=2 R\). Here, \(R\) is the gas constant. Initially, each side has a volume \(V_{0}\) and temperature \(T_{0}\). The left side has an electric heater, which is turned on at very low power to transfer heat \(Q\) to the gas on the left side. As a result the partition moves slowly towards the right reducing the right side volume to \(V_{0} / 2\). Consequently, the gas temperatures on the left and the right sides become \(T_{L}\) and \(T_{R}\), respectively. Ignore the changes in the temperatures of the cylinder, heater and the partition.

Question :
The value of $\frac{T_R}{T_0}$ is:

The area of the region
$\left\{(x,y):0\le x\le \frac{9}{4}, 0\le y\le 1, x\ge 3y, x+y\ge 2\right\}$ is

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An aqueous solution of a mixture of two inorganic salts, when treated with dilute \(H C\) ?, gave a precipitate \((\boldsymbol{P})\) and a filtrate \((\boldsymbol{Q})\). The precipitate \(\boldsymbol{P}\) was found to dissolve in hot water. The filtrate \((\boldsymbol{Q})\) remained unchanged, when treated with \(\mathrm{H}_{2} \mathrm{~S}\) in a dilute mineral acid medium. However, it gave a precipitate \((\boldsymbol{R})\) with \(H_{2} S\) in an ammoniacal medium. The precipitate \(\boldsymbol{R}\) gave a coloured solution \((\boldsymbol{S})\), when treated with \(\mathrm{H}_{2} \mathrm{O}_{2}\) in an aqueous \(\mathrm{NaOH}\) medium.
Question:
The coloured solution \(\boldsymbol{S}\) contains

The reaction of \(P_2\) with \(X\) leads selectively to \(\mathrm{P}_4 \mathrm{O}_6\). The \(\mathrm{X}\) is

Native silver metal forms a water soluble complex with a dilute aqueous solution of \(\mathrm{NaCN}\) in the presence of