Statement I Boron always forms covalent bond
Statement II The small size of \(\mathrm{B}^{3+}\) favours formation of covalent bond.

Total number of cis $\mathrm{N}-\mathrm{M}\mathrm{n}-\mathrm{C}\mathrm{l}$ bond angles (that is, $\mathrm{M}\mathrm{n}-\mathrm{N}$ and $\mathrm{M}\mathrm{n}-\mathrm{C}\mathrm{l}$ bonds in cis positions) present in a molecule of cis- $\left[\mathrm{M}\mathrm{n}{\left(\mathrm{e}\mathrm{n}\right)}_2{\mathrm{C}\mathrm{l}}_2\right]$ complex is _________ $\left(en={\mathrm{N}\mathrm{H}}_2{\mathrm{C}\mathrm{H}}_2{\mathrm{C}\mathrm{H}}_2{\mathrm{N}\mathrm{H}}_2\right)$

For the reaction, \(\mathbf{X}(s) \rightleftharpoons \mathbf{Y}(s)+\mathbf{Z}(g)\), the plot of \(\ln \frac{p_{\mathbf{Z}}}{p^{\theta}}\) versus \(\frac{10^{4}}{T}\) is given below (in solid line), where \(p_{\mathbf{Z}}\) is the pressure (in bar) of the gas \(\mathbf{Z}\) at temperature \(T\) and \(p^{\theta}=1\) bar.

(Given, \(\frac{\mathrm{d}(\ln K)}{\mathrm{d}\left(\frac{1}{T}\right)}=-\frac{\Delta H^{\theta}}{R}\), where the equilibrium constant, \(K=\frac{p_{z}}{p^{\theta}}\) and the gas constant, \(\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\) )
The value of $∆{\mathrm{S}}^{\mathrm{o}}$ (in $\mathrm{kJ} {\mathrm{mol}}^{-1}$) for the given reaction, at $1000 \mathrm{K}$ is ___.

For a reaction taking place in a container in equilibrium with its surroundings, the effect of temperature on its equilibrium constant $\mathrm{K}$ in terms of change in entropy is described by:

For the following reaction, the equilibrium constant ${\mathrm{K}}_{\mathrm{e}}$ at $298\mathrm{ }\mathrm{K}$ is $1.6\times {10}^{17}.$
$\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)+{\mathrm{S}}^{2-}\left(\mathrm{a}\mathrm{q}\right)\mathrm{ }\rightleftharpoons \mathrm{F}\mathrm{e}\mathrm{S}\left(\mathrm{s}\right)$
When equal volumes of $0.06\mathrm{ }\mathrm{M}\mathrm{ }\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)$ and $0.2\mathrm{ }\mathrm{M}{\mathrm{ }\mathrm{S}}^{2-}\left(\mathrm{a}\mathrm{q}\right)$ solutions are mixed, the equilibrium concentration of $\mathrm{F}{\mathrm{e}}^{2+}\left(\mathrm{a}\mathrm{q}\right)$ is found to be $\mathrm{Y}\times {10}^{-17}\mathrm{M}.$ The value of $\mathrm{Y}$ is __________

The increasing order of atomic radii of the following group $13$ elements is

Match the compounds in List-I with the appropriate observations in List-II and choose the correct option.

List - I	List - II
(P)	(1) Reaction with phenyl diazonium salt gives #ff0 dye.
(Q)	(2) Reaction with ninhydrin gives purple color and it also reacts with \(FeCl _3\) to give violet color.
(R)	(3) Reaction with glucose will give corresponding hydrazone.
(S)	(4) Lassiagne extract of the compound treated with dilute HCl followed by addition of aqueous \(FeCl _3\) gives blood red color.
	(5) After complete hydrolysis,it will give ninhydrin test and it DOES NOT give positive phthalein dye test.

Aqueous solutions of \(\mathrm{HNO}_3, \mathrm{KOH}\), \(\mathrm{CH}_3 \mathrm{COOH}\), and \(\mathrm{CH}_3 \mathrm{COONa}\) of identical concentrations are provided. The pair(s) of solutions which form a buffer upon mixing is(are)

If $M=\left(\begin{array}{cc}\frac{5}{2}& \frac{3}{2}\\ -\frac{3}{2}& -\frac{1}{2}\end{array}\right)$, then which of the following matrices is equal to $M^{2022}$ ?

Suppose a ${}_{88}{}^{226}Ra$ nucleus at rest and in ground state undergoes $\mathrm{\alpha }$ -decay to a ${}_{86}{}^{222}Rn$ nucleus in its excited state. The kinetic energy of the emitted $\mathrm{\alpha }$ particle is found to be $4.44\mathrm{ }\mathrm{M}\mathrm{e}\mathrm{V}.{}_{86}{}^{222}Rn$ nucleus then goes to its ground state by $\mathrm{\gamma }$ -decay. The energy of the emitted $\mathrm{\gamma }$ -photon is _______ $\mathrm{k}\mathrm{e}\mathrm{V},$
[Given: atomic mass of ${\mathrm{ }}_{88}^{226}\mathrm{R}\mathrm{a}=226.005\mathrm{u},$ atomic mass of ${\mathrm{ }}_{86}^{222}\mathrm{R}\mathrm{n}=222.000\mathrm{u},$ atomic mass of $\mathrm{\alpha }$ particle $=4.000\mathrm{u},1\mathrm{u}=931\mathrm{M}\mathrm{e}\mathrm{V}/{\mathrm{c}}^2,\mathrm{c}$ is speed of the light]

In the reaction,
$\text{P}+\text{Q}\to \text{R}+\text{S}$
the time taken for $75\%$ reaction of $\mathrm{P}$is twice the time taken for$50\%$ reaction of $\mathrm{P}$. The concentration of $\mathrm{Q}$varies with reaction time as shown in the figure.The overall order of the reaction is:

A free hydrogen atom after absorbing a photon of wavelength ${\mathrm{\lambda }}_{\mathrm{a}}$ gets excited from the state $\mathrm{n}=1$ to the state $\mathrm{n}=4.$ Immediately after that the electron jumps to $\mathrm{n}=\mathrm{m}$ state by emitting a photon of wavelength ${\mathrm{\lambda }}_{\mathrm{e}}.$ Let the change in momentum of atom due to the absorption and the emission are $\mathrm{\Delta }{\mathrm{p}}_{\mathrm{a}}$ and $\mathrm{\Delta }{\mathrm{p}}_{\mathrm{e}},$ respectively. If $\frac{{\mathrm{\lambda }}_{\mathrm{a}}}{{\lambda }_e}=\frac{1}{5}.$ Which of the option(s) is/are correct?
[Use $\mathrm{h}\mathrm{c}=1242\mathrm{e}\mathrm{V}\mathrm{n}\mathrm{m},1\mathrm{n}\mathrm{m}={10}^{-9}\mathrm{m},$ $\mathrm{h}$ and $\mathrm{c}$ are Planck's constant and speed of light, respectively]

Let $S=\left\{\mathrm{1,2},3,\dots .9\right\}$. For $k=\mathrm{1,2},\dots 5,$ let $N_k$ be the number of subsets of $S$, each containing five elements out of which exactly $k$ are odd. Then $N_1+N_2+N_3+N_4+N_5=$