Liquids A and B form ideal solution over the entire range of composition. At temperature $\mathrm{T}$, equimolar binary solution of liquids A and B has vapour pressure $45 \mathrm{T}\mathrm{o}\mathrm{r}\mathrm{r}$ . At the same temperature, a new solution of A and B having mole fractions ${\mathrm{x}}_{\mathrm{A}}\mathrm{ }\mathrm{and}\mathrm{ }{\mathrm{x}}_{\mathrm{B}}$, respectively, has vapour pressure of $22.5 \mathrm{T}\mathrm{o}\mathrm{r}\mathrm{r}$. The value of $\frac{{\mathrm{x}}_{\mathrm{A}}}{{\mathrm{x}}_{\mathrm{B}}}$, in the new solution is ____.
(Given that the vapour pressure of pure liquid A is $20 \mathrm{Torr}$ at temperature $\mathrm{T}$)

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A fixed mass $\text{'}\mathrm{m}\text{'}$ of a gas is subjected to transformation of states from $\mathrm{K}$ to $\mathrm{L}$ to $\mathrm{M}$ to $\mathrm{N}$ and back to $\mathrm{K}$ as shown in the figure

Question :
The pair of isochoric processes among the transformation of states is

The total number of chiral molecules formed from one molecule of $P$ on complete ozonolysis $\left({\mathrm{O}}_3,\mathrm{Zn}/H_2\mathrm{O}\right)$ is _____

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Carbon-14 is used to determine the age of organic material. The procedure is based on the formation of \({ }^{14} \mathrm{C}\) by neutron capture in the upper atmosphere.
\(
{ }_7^{14} \mathrm{~N}+{ }_0^1 n \longrightarrow{ }_6^{14} \mathrm{C}+{ }_1 n^1
\)
\({ }^{14} \mathrm{C}\) is absorbed by living organisms during photosynthesis. The \({ }^{14} \mathrm{C}\) content is constant in living organism once the plant or animal dies, the uptake of carbon dioxide by it ceases and the level of \({ }^{14} \mathrm{C}\) in the dead being, falls to the decay which \({ }^{14} \mathrm{C}\) undergoes.
\(
{ }_6^{14} \mathrm{C} \longrightarrow{ }_7^{14} \mathrm{~N}+\beta^{-}
\)
The half life period of \({ }^{14} \mathrm{C}\) is 5770 years. The decay constant \((\lambda)\) can be calculated by using the following formula \(\lambda=\frac{0.693}{t_{1 / 2}}\).
The comparison of the \(\beta^{-}\)activity of the dead matter with that of the carbon still in circulation enables measurement of the period of the isolation of the material from the living cycle. The method however, ceases to be accurate over periods longer than 30,000 years. The proportion of \({ }^{14} \mathrm{C}\) to \({ }^{12} \mathrm{C}\) in living matter is \(1: 10^{12}\).
Question:
A nuclear explosion has taken place leading to increase in concentration of \(C^{14}\) in nearby areas. \(\mathrm{C}^{14}\) concentration is \(C_1\) in nearby areas and \(C_2\) in areas far away. If the age of the fossil is determined to be \(T_1\) and \(T_2\) at the places respectively then

The correct option(s) related to the extraction of iron from its ore in the blast furnace operating in the temperature range $900-1500 \mathrm{K}$ is(are)

The cubic unit cell structure of a compound containing cation $\mathrm{M}$ and anion $\mathrm{X}$ is shown below. When compared to the anion, the cation has smaller ionic radius. Choose the correct statement(s).

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\(\mathbf{X}\) and \(\mathbf{Y}\) are two volatile liquids with molar weights of \(10 \mathrm{~g} \mathrm{~mol}^{-1}\) and \(40 \mathrm{~g} \mathrm{~mol}^{-1}\) respectively. Two cotton plugs, one soaked in \(\mathbf{X}\) and the other soaked in \(\mathbf{Y}\), are simultaneously placed at the ends of a tube of length \(L=24 \mathrm{~cm}\), as shown in the figure. The tube is filled with an inert gas at \(1\) atmosphere pressure and a temperature of \(300 \mathrm{~K}\). Vapours of \(\mathbf{X}\) and \(\mathbf{Y}\) react to form a product which is first observed at a distance \(\mathbf{d} \mathrm{~cm}\) from the plug soaked in \(\mathbf{X}\). Take \(\mathbf{X}\) and \(\mathbf{Y}\) to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.



Question:

The experimental value of \(\mathbf{d}\) is found to be smaller than the estimate obtained using Graham's law. This is due to

In terms of potential difference $V$ , electic current $I$ , permittivity ${\epsilon }_0$ , permeability ${\mu }_0$ and speed of light $c$ , the dimensionally correct equation(s) is (are)

The reaction of $4$-methyloct-$1$-ene $(\mathrm{P},2.52 \mathrm{g})$ with $\mathrm{HBr}$ in the presence of ${\left({\mathrm{C}}_6{\mathrm{H}}_5\mathrm{CO}\right)}_2{\mathrm{O}}_2$ gives two isomeric bromides in a $9: 1$ ratio, with a combined yield of $50\%$. Of these, the entire amount of the primary alkyl bromide was reacted with an appropriate amount of diethylamine followed by treatment with aq. ${\mathrm{K}}_2{\mathrm{CO}}_3$ to give a non-ionic product $\mathrm{S}$ in $100\%$ Yield. The mass (in $\mathrm{mg}$ ) of $\mathrm{S}$ obtained is
[Use molar mass (in ${\mathrm{gmol}}^{-1}$ ): $\mathrm{H}=1,\mathrm{C}=12, \mathrm{N}=14,\mathrm{Br}=80$ ]

Two spherical bodies \(A\) (radius \(6 \mathrm{~cm}\) ) and \(B\) (radius \(18 \mathrm{~cm}\) ) are at temperatures \(T_1\) and \(T_2\), respectively. The maximum intensity in the emission spectrum of \(A\) is at \(500 \mathrm{~nm}\) and in that of \(B\) is at \(1500 \mathrm{~nm}\). Considering them to be black bodies, what will be the ratio of the rate of total energy radiated by \(A\) to that of \(B\) ?

The species having bond order different from that in \(\mathrm{CO}\) is

If \(\mathbf{a}, \mathbf{b}, \mathbf{c}\) and \(\mathbf{d}\) are the unit vectors such that \((\mathbf{a} \times \mathbf{b}) \cdot(\mathbf{c} \times \mathbf{d})=1\) and \(\mathbf{a} \cdot \mathbf{c}=\frac{1}{2}\), then

The total number of lone pairs of electrons in ${\mathrm{N}}_2{\mathrm{O}}_3$ is