The species having bond order different from that in \(\mathrm{CO}\) is

The crystalline form of borax has

The IUPAC name of \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{COCl}\) is

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An acylic hydrocarbon \(P\), having molecular formula \(\mathrm{C}_6 \mathrm{H}_{10}\), gave acetone as the only organic product through the following sequence of reactions, in which \(Q\) is an intermediate organic compounds.

Question:
The structure of compound P is

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Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite \(\left(\mathrm{CuSO}_4 \cdot 5 \mathrm{H}_2 \mathrm{O}\right)\), atacamite \(\left(\mathrm{Cu}_2 \mathrm{Cl}(\mathrm{OH})_3\right)\), cuprite \(\left(\mathrm{Cu}_2 \mathrm{O}\right)\), copper glance \(\left(\mathrm{Cu}_2 \mathrm{~S}\right)\) and malachite \(\left(\mathrm{Cu}_2(\mathrm{OH})_2 \mathrm{CO}_3\right)\). However, 80\% of the world copper production comes from the ore chalcopyrite \(\left(\mathrm{CuFeS}_2\right)\). The extraction of copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.
Question:
Partial roasting of chalcopyrite produces

The number of hydroxyl group(s) in Q is

For a double strand DNA, one strand is given below:

The amount of energy required to split the double strand DNA into two single strands is _______ kcal \(\mathrm{mol}^{-1}.\)
[Given: Average energy per \(\mathrm{H}\)-bond for A-T base pair \(=1.0 \mathrm{kcal} \mathrm{mol}^{-1}, \mathrm{G}-\mathrm{C}\) base pair \(=1.5 \mathrm{kcal}\) \(\mathrm{mol}^{-1}\), and A-U base pair \(=1.25 \mathrm{kcal} \mathrm{mol}^{-1}.\) Ignore electrostatic repulsion between the phosphate groups.]

The number of points in $\left(-\infty ,\infty \right)$, for which $x^2-x\sin x-\cos x=0$, is:

Columns 1, 2 and 3 contain starting materials, reaction conditions and type of reactions respectively.

Column 1	Column 2	Column 3
(I) Toulene	(i) \(NaOH\) \( /Br _2\)	(P) Condensation
(II) Acetophenone	(ii) \(B r_2 / h v\)	(Q) Carboxylation
(III) Benzaldehyde	(iii) \(\left( CH _3 CO \right)_2\) \(O / CH _3\) \(COOK\)	(R) Substitution
(IV) Phenol	(iv) \(NaOH\) \(/CO _2\)	(S) Haloform

The only CORRECT combination that gives two different carboxylic acids is

Let $\mathrm{M}=\left[\begin{array}{cc}{\sin }^4\mathrm{\theta }& -1-{\sin }^2\mathrm{\theta }\\ 1+{\cos }^2\mathrm{\theta }& {\cos }^4\mathrm{\theta }\end{array}\right]=\mathrm{\alpha }\mathrm{I}+\mathrm{\beta }{\mathrm{M}}^{-1},$ where $\mathrm{\alpha }=\mathrm{\alpha }\left(\mathrm{\theta }\right)$ and $\mathrm{\beta }=\mathrm{\beta }\left(\mathrm{\theta }\right)$ are real number, and $\mathrm{I}$ is the $2\times 2$ identity matrix. If ${\mathrm{\alpha }}^{\mathrm{*}}$ is the minimum of the set { $\mathrm{\alpha }\left(\mathrm{\theta }\right):\mathrm{\theta }\in \left[0,\mathrm{ }2\mathrm{\pi }\right)\}$ and ${\mathrm{\beta }}^{\mathrm{*}}$ is the minimum of the set $\left\{\mathrm{\beta }\left(\mathrm{\theta }\right):\mathrm{\theta }\in \left[0,\mathrm{ }2\mathrm{\pi }\right)\right\},$ then the value of ${\mathrm{\alpha }}^{\mathrm{*}}+{\mathrm{\beta }}^{\mathrm{*}}$ is

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A small spherical monoatomic ideal gas bubble \(\left(\gamma=\frac{5}{3}\right)\) is trapped inside a liquid of density \(\rho_1\) (see figure). Assume that the bubble does not exchange any heat with the liquid. The bubble contains \(n\) moles of gas. The temperature of the gas when the bubble is at the bottom is \(T_0\), the height of the liquid is \(H\) and the atmospheric pressure is \(p_0\) (Neglect surface tension).

Question:
As the bubble moves upwards, besides the buoyancy force the following forces are acting on it.

The heating of \(\mathrm{NH}_4 \mathrm{NO}_2\) at \(60-70^{\circ} \mathrm{C}\) and \(\mathrm{NH}_4 \mathrm{NO}_3\) at \(200-250^{\circ} \mathrm{C}\) is associated with the formation of nitrogen containing compounds \(\mathbf{X}\) and \(\mathbf{Y}\), respectively. \(\mathbf{X}\) and \(\mathbf{Y}\), respectively, are

The nitrogen oxide(s) that contain(s) N.N bond(s) is (are)