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JEE Advanced · Chemistry · 24. Haloalkanes & Haloarenes

The reaction of 4-methyloct-1-ene (P,2.52 g) with HBr in the presence of C6H5CO2O2 gives two isomeric bromides in a 9: 1 ratio, with a combined yield of 50%. Of these, the entire amount of the primary alkyl bromide was reacted with an appropriate amount of diethylamine followed by treatment with aq. K2CO3 to give a non-ionic product S in 100% Yield. The mass (in mg ) of S obtained is
[Use molar mass (in gmol-1 ): H=1,C=12, N=14,Br=80 ]

  1. A 1780
  2. B 1791
  3. C 1500
  4. D 2165
Verified Solution

Answer & Solution

Correct Answer

(B) 1791

Step-by-step Solution

Detailed explanation

The 1-alkene undergo addition reaction and major product formed according to anti-Markonikov's rule. Moles of P =Mass of PMolar mass of P=2.52252=0.01 mol
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