In the scheme given below, the total number of intramolecular aldol condensation products formed from ' \(Y\) ' is

Hydrogen bonding plays a central role in the following phenomena:

In the given reaction scheme, $\mathbf{P}$ is a phenyl alkyl ether, $\mathbf{Q}$  is an aromatic compound; $\mathbf{R}$ and $\mathbf{S}$ are the major products.

The correct statement about $\mathbf{S}$ is

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Thermal decomposition of gaseous \(\mathrm{X}_{2}\) to gaseous \(\mathrm{X}\) at \(298 \mathrm{~K}\) takes place according to the following equation:

\(\mathrm{X}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{X}(\mathrm{g})\)

The standard reaction Gibbs energy, \(\Delta_{r} G^{\circ}\), of this reaction is positive. At the start of the reaction, there is one mole of \(\mathrm{X}_{2}\) and no \(\mathrm{X}\). As the reaction proceeds, the number of moles of \(\mathrm{X}\) formed is given by \(\beta\). Thus, \(\beta_{\text {equilibrium }}\) is the number of moles of \(\mathrm{X}\) formed at equilibrium. The reaction is carried out at a constant total pressure of \(2\) bar. Consider the gases to behave ideally. (Given : \(R=0.083 \mathrm{~L}\) bar \(\mathrm{K}^{-1} \mathrm{~mol}^{-1}\) )

Question:
The equilibrium constant \(K_{P}\) for this reaction at \(298 \mathrm{~K},\) in terms of \(\beta_{equilibrium}\) is

The reagent(s) used for softening the temporary hardness of water is(are)

In the chemical reaction between stoichiometric quantities of ${\mathrm{KMnO}}_4$ $\mathrm{KI}$ in weakly basic solution, what is the number of moles of ${\mathrm{I}}_2$ released for $4$ ${\mathrm{KMnO}}_4$ consumed?

Match the rate expressions in LIST-I for the decomposition of \(\mathrm{X}\) with the corresponding profiles provided in LIST-II. \(X_s\) and \(\mathrm{k}\) are constants having appropriate units.

The conductance of $0.0015\mathrm{ }\mathrm{M}$ aqueous solution of a weak monobasic acid was determined by using a conductivity cell consisting of platinized $\mathrm{Pt}$electrodes. The distance between the electrodes is $120\mathrm{ }\mathrm{cm}$ with an area of cross-section of $1 {\mathrm{cm}}^2$. The conductance of this solution was found to be $5\times {10}^{-7}\mathrm{S}$ . The $\mathrm{pH}$of the solution is $4$. The value of limiting molar conductivity of this weak monobasic acid in aqueous solution is $\mathrm{ }\mathrm{Z}\mathrm{ }\times \mathrm{ }{10}^2\mathrm{S}\mathrm{ }{\mathrm{cm}}^{-1}{\mathrm{mol}}^{-1}.$ The value of $\mathrm{Z}$is.

The compound (s) having peroxide linkage is(are) :

The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions of KCl, $\mathrm{C}{\mathrm{H}}_3\mathrm{O}\mathrm{H}\mathrm{}$ and $\mathrm{C}{\mathrm{H}}_3{\left(\mathrm{C}{\mathrm{H}}_2\right)}_{11}\mathrm{O}\mathrm{S}{\mathrm{O}}_3^{-}\mathrm{}\mathrm{N}{\mathrm{a}}^{+}$ at room temperature. The correct assignment of the sketches is -

A metal rod of length \(L\) and mass \(m\) is pivoted at one end. A thin disc of mass \(M\) and radius \(R( < L)\) is attached at its centre to the free end of the rod. Consider two ways the disc is attached. Case A-the disc is not free to rotate about its centre and case \(B\)-the disc is free to rotate about its centre. The rod-disc system performs
SHM in vertical plane after being released from the same displaced position. Which of the following statement(s) is/are true?

Assuming that Hund's rule is violated, the bond order and magnetic nature of the diatomic molecule \(\mathrm{B}_2\) is

A circular disc of radius $R$ carries surface charge density $\sigma \left(r\right)={\sigma }_0\left(1-\frac{r}{R}\right)$, where ${\sigma }_0$ is a constant and $r$ is the distance from the center of the disc. Electric flux through a large spherical surface that encloses the charged disc completely is ${\varphi }_0$. Electric flux through another spherical surface of radius $\frac{R}{4}$ and concentric with the disc is $\varphi$. Then the ratio $\frac{{\varphi }_0}{\varphi }$ is