JEE Advanced · Chemistry · 7. Chemical Equilibrium
Paragraph:
Thermal decomposition of gaseous \(\mathrm{X}_{2}\) to gaseous \(\mathrm{X}\) at \(298 \mathrm{~K}\) takes place according to the following equation:
\(\mathrm{X}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{X}(\mathrm{g})\)
The standard reaction Gibbs energy, \(\Delta_{r} G^{\circ}\), of this reaction is positive. At the start of the reaction, there is one mole of \(\mathrm{X}_{2}\) and no \(\mathrm{X}\). As the reaction proceeds, the number of moles of \(\mathrm{X}\) formed is given by \(\beta\). Thus, \(\beta_{\text {equilibrium }}\) is the number of moles of \(\mathrm{X}\) formed at equilibrium. The reaction is carried out at a constant total pressure of \(2\) bar. Consider the gases to behave ideally. (Given : \(R=0.083 \mathrm{~L}\) bar \(\mathrm{K}^{-1} \mathrm{~mol}^{-1}\) )
Question:
The equilibrium constant \(K_{P}\) for this reaction at \(298 \mathrm{~K},\) in terms of \(\beta_{equilibrium}\) is
- A
- B
- C
- D
Answer & Solution
Correct Answer
(B)
Step-by-step Solution
Detailed explanation
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- dissociates in and ions in an aqueous solution, with a degree of dissociation of 0.5. The ratio of the observed depression of freezing point of the aqueous solution to the value of the depression of freezing point in the absence of ionic dissociation isJEE Advanced 2014 Medium
- If the freezing point of a 0.01 molal aqueous solution of a cobalt (III) chloride-ammonia complex (which behaves as a strong electrolyte) is , the number of chloride(s) in the coordination sphere of the complex isJEE Advanced 2015 Medium
- The pair(s) of ions where BOTH the ions are precipitated upon passing gas in presence of dilute HCl, is (are)JEE Advanced 2015 Easy
- Passing \(\mathrm{H}_2 \mathrm{~S}\) gas into a mixture of \(\mathrm{Mn}^{2+}, \mathrm{Ni}^{2+}, \mathrm{Cu}^{2+}\) and \(\mathrm{Hg}^{2+}\) ions in an acidified aqueous solution precipitatesJEE Advanced 2011 Medium
- The direct conversion of \(A\) to \(B\) is difficult, hence it is carried out by the following shown path.

Given \(\Delta S_{(A \rightarrow C)}=50 \mathrm{eu}, \quad \Delta S_{(C \rightarrow D)}=30 \mathrm{eu}, \quad\) \(\Delta S_{(B \rightarrow D)}=20 \mathrm{eu}\) where eu is entropy unit, then \(\Delta S_{(A \rightarrow B)}\) isJEE Advanced 2006 Medium - At \(298 \mathrm{~K}\), the limiting molar conductivity of a weak monobasic acid is \(4 \times 10^{2} \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}\). At \(298 \mathrm{~K}\), for an aqueous solution of the acid the degree of dissociation is \(\boldsymbol{\alpha}\) and the molar conductivity is \(\mathbf{y} \times 10^{2} \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}\). At \(298 \mathrm{~K}\), upon 20 times dilution with water, the molar conductivity of the solution becomes \(3 \mathbf{y} \times 10^{2} \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}\)
The value of is _________ .JEE Advanced 2021 Hard
More PYQs from JEE Advanced
- The concentration of \(R\) in the reaction \(R \longrightarrow P\) was measured as a function of time and the following data is obtained :
\(\begin{array}{lllll}{[R] \text { (molar) }} & 1.0 & 0.75 & 0.40 & 0.10 \\ t \text { (min) } & 0.0 & 0.05 & 0.12 & 0.18\end{array}\)
The order of the reaction isJEE Advanced 2010 Easy - A circular wire loop of radius \(R\) is placed in the \(x-y\) plane centered at the origin \(O\). A square loop of side \(a(a< < R)\) having two turns is placed with its centre at \(z=\sqrt{3} R\) along the axis of the circular wire loop, as shown in figure.

The plane of the square loop makes an angle of \(45^{\circ}\) with respect to the \(z\)-axis. If the mutual inductance between the loops is given by \(\frac{\mu_{0} a^{2}}{2^{p / 2} R}\), then the value of \(p\) isJEE Advanced 2012 Hard - The densities of two solid spheres and of the same radii vary with radial distance as and , respectively, where is a constant. The moments of inertia of the individual spheres about axes passing through their centres are and , respectively. If , the value of isJEE Advanced 2015 Hard
- Let and let and
Then which of the following options is/are correct?JEE Advanced 2019 Hard - A block of mass another mass , are placed together (see figure) on an inclined plane with angle of inclination . Various values of are given in List I. The coefficient of friction between the block and the plane is always zero. The coefficient of static and dynamic friction between the block and the plane are equal to . In List II expressions for the friction on the block are given. Match the correct expression of the friction in List II with the angles given in List I, and choose the correct option. The acceleration due to gravity is denoted by g.
[Useful information: ]
List I List II A. B. C. D. JEE Advanced 2014 Medium - Consider boxes, where each box contains red balls and blue balls. Assume that all balls are distinct. In how many different ways can balls be chosen from these boxes so that from each box at least one red ball and one blue ball are chosen?JEE Advanced 2022 Hard