Assuming that Hund's rule is violated, the bond order and magnetic nature of the diatomic molecule \(\mathrm{B}_2\) is

A list of species having the formula XZ4 is given below.
\(\text{XeF} _4, \text{SF} _4, \text{SiF} _4, \text{BF} _4^{-}, \text{BrF} _4^{-},\left[\text{Cu} \left(\text{NH} _3\right)_4\right]^{2+},\) \(\left[\text{FeCl} _4\right]^{2-},\left[\text{CoCl} _4\right]^{2-}\) and \(\left[\text{PtCl} _4\right]^{2-}\)
Defining shape on the basis of the location of X and Z atoms, the total number of species having a square planar shape is

For the reaction, \(2 \mathrm{CO}+\mathrm{O}_2 \rightarrow 2 \mathrm{CO}_2 ; \Delta H=-560 \mathrm{~kJ}\). Two moles of \(\mathrm{CO}\) and one mole of \(\mathrm{O}_2\) are taken in a container of volume \(1 \mathrm{~L}\). They completely form two moles of \(\mathrm{CO}_2\), the gases deviate appreciably from ideal behaviour. If the pressure in the vessel changes from 70 to \(40 \mathrm{~atm}\), find the magnitude (absolute value) of \(\Delta U\) at \(500 \mathrm{~K} .(1 \mathrm{~L}-\mathrm{atm}=0.1 \mathrm{~kJ})\)

The boiling point of water in a \(0.1\) molal silver nitrate solution (solution \(\mathbf{A}\) ) is \(\mathbf{x}^{\circ} \mathrm{C}\). To this solution \(\mathbf{A}\), an equal volume of \(0.1\) molal aqueous barium chloride solution is added to make a new solution B. The difference in the boiling points of water in the two solutions \(\mathbf{A}\) and \(\mathbf{B}\) is \(\mathbf{y} \times 10^{-2}{ }^{\circ} \mathrm{C}\).
(Assume: Densities of the solutions \(\mathbf{A}\) and \(\mathbf{B}\) are the same as that of water and the soluble salts dissociate completely.
Use: Molal elevation constant (Ebullioscopic Constant), \(K_{b}=0.5 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\); Boiling point of pure water as \(100^{\circ} \mathrm{C}\).)
The value of $\mathrm{x}$ is ___.

The concentration of \(R\) in the reaction \(R \longrightarrow P\) was measured as a function of time and the following data is obtained :
\(\begin{array}{lllll}{[R] \text { (molar) }} & 1.0 & 0.75 & 0.40 & 0.10 \\ t \text { (min) } & 0.0 & 0.05 & 0.12 & 0.18\end{array}\)
The order of the reaction is

For the reaction, \(\mathbf{X}(s) \rightleftharpoons \mathbf{Y}(s)+\mathbf{Z}(g)\), the plot of \(\ln \frac{p_{\mathbf{Z}}}{p^{\theta}}\) versus \(\frac{10^{4}}{T}\) is given below (in solid line), where \(p_{\mathbf{Z}}\) is the pressure (in bar) of the gas \(\mathbf{Z}\) at temperature \(T\) and \(p^{\theta}=1\) bar.

(Given, \(\frac{\mathrm{d}(\ln K)}{\mathrm{d}\left(\frac{1}{T}\right)}=-\frac{\Delta H^{\theta}}{R}\), where the equilibrium constant, \(K=\frac{p_{z}}{p^{\theta}}\) and the gas constant, \(\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\) )
The value of $∆{\mathrm{S}}^{\mathrm{o}}$ (in $\mathrm{kJ} {\mathrm{mol}}^{-1}$) for the given reaction, at $1000 \mathrm{K}$ is ___.

Choose the correct statement(s) among the following:

The correct order of acid strength of the following carboxylic acids is -

Let \(P\left(x_1, y_1\right)\) and \(Q\left(x_2, y_2\right)\) be two distinct points on the ellipse
\(\frac{x^2}{9}+\frac{y^2}{4}=1\)
such that \(y_1>0\), and \(y_2>0\). Let C denote the circle \(x^2+y^2=9\), and \(M\) be the point \((3,0)\).
Suppose the line \(x=x_1\) intersects \(C\) at \(R\), and the line \(x=x_2\) intersects \(C\) at \(S\), such that the \(y\)-coordinates of \(R\) and \(S\) are positive. Let \(\angle R O M=\frac{\pi}{6}\) and \(\angle S O M=\frac{\pi}{3}\), where \(O\) denotes the origin \((0,0)\). Let \(|X Y|\) denote the length of the line segment \(X Y\).
Then which of the following statements is (are) TRUE?

A conducting solid sphere of radius \(R\) and mass \(M\) carries a charge \(Q\). The sphere is rotating about an axis passing through its center with a uniform angular speed \(\omega\). The ratio of the magnitudes of the magnetic dipole moment to the angular momentum about the same axis is given as \(\alpha \frac{Q}{2 M}\). The value of \(\alpha\) is _______ .

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Let \(A\) be the set of all \(3 \times 3\) symmetric matrices all of whose entries are either 0 or 1 . Five of these entries are 1 and four of them are 0 .Question:
The number of matrices \(A\) in \(A\) for which the system of linear equations \(A\left[\begin{array}{l}x \\ y \\ z\end{array}\right]=\left[\begin{array}{l}1 \\ 0 \\ 0\end{array}\right]\) is is inconsistent, is

In the reaction scheme shown below,$\mathrm{Q},\mathrm{R},$ and$\mathrm{S}$ are the major products.

The correct structure of

The mole fraction of urea in an aqueous urea solution containing $900\mathrm{ }\mathrm{g}$ of water is $0.05$ . If the density of the solution is $1.2\mathrm{ }\mathrm{g}\mathrm{ }{\mathrm{c}\mathrm{m}}^{-3}$ , the molarity of urea solution is _______
(Given data: Molar masses of urea and water are $60\mathrm{ }\mathrm{g}\mathrm{ }{\mathrm{m}\mathrm{o}\mathrm{l}}^{-1}$ and $18\mathrm{ }\mathrm{g}\mathrm{ }{\mathrm{m}\mathrm{o}\mathrm{l}}^{-1}$ , respectively)