The compound (s) having peroxide linkage is(are) :

On complete hydrogenation, natural rubber produces

Scheme $1$ and $2$ describe the conversion of $\mathrm{P}$ to $\mathrm{Q}$ and $\mathrm{R}$ to $\mathrm{S},$ respectively. Scheme $3$ describes the synthesis of $\mathrm{T}$ from $\mathrm{Q}$ and $\mathrm{S}.$ The total number of $\mathrm{B}\mathrm{r}$ atoms in a molecule of $\mathrm{T}$ is
Scheme $1$:

Scheme $2$:

Scheme$3$:

Paragraph: When potassium iodide is added to an aqueous solution of potassium ferricyanide, a reversible reaction is observed in which a complex \(\mathbf{P}\) is formed. In a strong acidic medium, the equilibrium shifts completely towards \(\mathbf{P}\). Addition of zinc chloride to \(\mathbf{P}\) in a slightly acidic medium results in a sparingly soluble complex Q.
Question: The number of zinc ions present in the molecular formula of \(\mathbf{Q}\) is

Choose the reaction(s) from the following options, for which the standard enthalpy of reaction is equal to the standard enthalpy of formation.

The correct statement(s) about the compound given below is are

The plot of ${\mathrm{logk}}_{\mathrm{f}}$ versus $\frac{1}{\mathrm{T}}$ for a reversible reaction $\mathrm{A}\left(\mathrm{g}\right)\rightleftharpoons \mathrm{P}\left(\mathrm{g}\right)$ is shown.

Pre-exponential factors for the forward and backward reactions are ${10}^{15} {\mathrm{s}}^{-1}$ and ${10}^{11} {\mathrm{s}}^{-1}$, respectively. If the value of $\mathrm{logK}$ for the reaction at $500 \mathrm{K}$ is $6$, the value of $\left|{\mathrm{logk}}_{\mathrm{b}}\right|$ at $250 \mathrm{K}$ is
$\left[\mathrm{K}=\right.$equilibrium constant of the reaction, ${\mathrm{k}}_{\mathrm{f}}=$rate constant of forward reaction, ${\mathrm{K}}_{\mathrm{b}}=$rate constant of backward reaction]

Isomers of hexane, based on their branching, can be divided into three distinct classes as shown in the figure.

The correct order of their boiling point is

Paragraph:

A thermal power plant produces electric power of \(600 \mathrm{~kW}\) at \(4000 \mathrm{~V}\), which is to be transported to a place \(20 \mathrm{~km}\) away from the power plant for consumers' usage. It can be transported either directly with a cable of large current carrying capacity or by using a combination of step-up and step-down transformers at the two ends. The drawback of the direct transmission is the large energy dissipation. In the method using transformers, the dissipation is much smaller. In this method, a step-up transformer is used at the plant side so that the current is reduced to a smaller value. At the consumers' end, a step-down transformer is used to supply power to the consumers at the specified lower voltage. It is reasonable to assume that the power cable is purely resistive and the transformers are ideal with a power factor unity. All the currents and voltages mentioned are rms values.


Question:

If the direct transmission method with a cable of resistance \(0.4 \Omega \mathrm{km}^{-1}\) is used, the power dissipation (in %) during transmission is

Paragraph:

Let \(F_{1}\left(x_{1}, 0\right)\) and \(F_{2}\left(x_{2}, 0\right)\), for \(x_{1}<0\) and \(x_{2}>0\), be the foci of the ellipse \(\frac{x^{2}}{9}+\frac{y^{2}}{8}=1 .\) Suppose a parabola having vertex at the origin and focus at \(F_{2}\) intersects the ellipse at point \(M\) in the first quadrant and at point \(N\) in the fourth quadrant.


Question:

If the tangents to the ellipse at \(M\) and \(N\) meet at \(R\) and the normal to the parabola at \(M\) meets the \(x\)-axis at \(Q\), then the ratio of area of the triangle \(M Q R\) to area of the quadrilateral \(M F_{1} N F_{2}\) is

A ball is projected from the ground at an angle of ${45}^o$ with the horizontal surface. It reaches a maximum height of $120\mathrm{ m}$ and returns to the ground. Upon hitting the ground for the first time, it loses half of its kinetic energy. Immediately after the bounce, the velocity of the ball makes an angle of ${30}^o$ with the horizontal surface. The maximum height it reaches after the bounce (in meters) is _____________.

Paragraph:
Tollen's reagent is used for the detection of aldehyde when a solution of \(\mathrm{AgNO}_3\) is added to glucose with \(\mathrm{NH}_4 \mathrm{OH}\) then gluconic acid is formed
\(\mathrm{Ag}^{+}+e^{-} \rightarrow \mathrm{Ag} E_{\text {red }}^{\circ}=0.8 \mathrm{~V} \)
\( \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{H}_2 \mathrm{O} \rightarrow \text { Gluconic acid }\)\(\left(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_7\right)+2 \mathrm{H}^{+}+2 e^{-} ; -E_{\mathrm{red}}^{\circ}=\) \(-0.05 \mathrm{~V} \)
\( \mathrm{Ag}\left(\mathrm{NH}_3\right)_2^{+}+e^{-} \rightarrow \mathrm{Ag}(s)+2 \mathrm{NH}_3 ;\) \(E_{\mathrm{red}}^{\circ}=0.337 \mathrm{~V}\)
[Use \(2.303 \times \frac{R T}{F}=0.0592\) and \(\frac{F}{R T}=38.92\) at \(298 \mathrm{~K}\) ]
Question:
Ammonia is always added in this reaction. Which of the following must be incorrect?

Two identical plates P and Q , radiating as perfect black bodies, are kept in vacuum at constant absolute temperatures \(\mathrm{T}_{\mathrm{P}}\) and \(\mathrm{T}_{\mathrm{Q}}\), respectively, with \(\mathrm{T}_{\mathrm{Q}}<\mathrm{T}_{\mathrm{P}}\), as shown in Fig. 1. The radiated power transferred per unit area from P to Q is \(W_0\). Subsequently, two more plates, identical to P and Q, are introduced between P and Q, as shown in Fig. 2. Assume that heat transfer takes place only between adjacent plates. If the power transferred per unit area in the direction from P to Q (Fig. 2) in the steady state is \(W_S\), then the ratio \(\frac{W_0}{W_S}\) is ________.