Different possible thermal decomposition pathways for peroxyesters are shown below. Match each pathway from List I with an appropriate structure from List II and select the correct answer using the code given below the lists.

	List – I		List – II
A	Pathway P	P.
B.	Pathway Q	Q.
C.	Pathway R	R.
D.	Pathway S	S.

Consider the following molecules : ${\mathrm{Br}}_3{\mathrm{O}}_8, {\mathrm{F}}_2\mathrm{O},{\mathrm{H}}_2 {\mathrm{S}}_4{\mathrm{O}}_6,{\mathrm{H}}_2 {\mathrm{S}}_5{\mathrm{O}}_6$, and ${\mathrm{C}}_3{\mathrm{O}}_2$. Count the number of atoms existing in their zero oxidation state in each molecule. Their sum is

The correct statement(s) regarding defects in solids is (are)

The pair(s) of complexes wherein both exhibit tetrahedral geometry is(are)
(Note: $\mathrm{py}=$ pyridine Given: Atomic numbers of $\mathrm{Fe}, \mathrm{Co}, \mathrm{Ni}$ and $\mathrm{Cu}$ are $26, 27, 28$ and $29$, respectively)

The correct option(s) regarding the complex ${\left[Co\left(en\right){\left(N{H}_3\right)}_3\left(H_{2}O\right)\right]}^{3+}$ :-
(en $= H_{2}NC{H}_{2}C{H}_{2}N{H}_2$ ) is (are)

Both \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) and \(\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}\) are diamagnetic. The hybridisations of nickel in these complexes, respectively, are

The wave function, ${\mathrm{\psi }}_{\mathrm{n},\mathrm{}\mathrm{l},\mathrm{}{\mathrm{m}}_{\mathrm{l}}}$ is a mathematical function whose value depends upon spherical polar coordinates $\left(\mathrm{r},\mathrm{}\mathrm{\theta },\mathrm{}\mathrm{\varphi }\right)$ of the electron and characterized by the quantum numbers $\mathrm{n},\mathrm{}\mathrm{l}$ and ${\mathrm{m}}_{\mathrm{l}}$ . Here $\mathrm{r}$ is the distance from the nucleus, $\mathrm{\theta }$ is colatitude and $\mathrm{\varphi }$ is azimuth. In the mathematical functions given in the Table, $\mathrm{Z}$is the atomic number and ${\mathrm{a}}_{\mathrm{o}}$ is Bohr radius

Column 1	Column 2	Column 3
(I) 1s orbital	\(\begin{array}{l}\text { (i) } \psi_{ n , 1, m_1} \\ \propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{3}{2}} e ^{-\left(\frac{ Zr }{ e _{ o }}\right)}\end{array}\)	(P)
(II) 2s orbital	(ii) One radial node	(Q) Probability density at the nucleus \(\propto \frac{1}{ a _{ o }^3}\).
(III) \(2 p _{ z }\) orbital	\(\begin{array}{l}\text { (iii) } \psi_{ n }, 1, m_{ l } \\ \propto\left(\frac{ Z }{ a _{ o }}\right)^{\frac{5}{2}} re ^{-\left(\frac{ Zr }{2 a _{ o }}\right)} \cos \theta\end{array}\)	(R) Probability density is maximum at the nucleus.
(IV) \(3 d_{ z }^2\) orbital	(iv) \(x y\)-plane is a nodal plane	(S) Energy needed to excite an electron from \(n =2\) state to \(n =4\) state is \(\frac{27}{32}\) times the energy needed to excite are electron from \(n =2\) state to \(n =6\) state.

For the given orbital in column 1, the only correct combination for any hydrogen-like species is

Let \(m\) be the smallest positive integer such that the coefficient of \(x^2\) in the expansion of \((1+x)^2 +(1+x)^3+\ldots+(1+x)^{49}\) \(+~(1+m x)^{50}\) is \((3 n+1){ }^{51} C_3\) for some positive integer n . Then the value of \(n\) is

A circular coil of radius $R$ and $N$ turns has negligible resistance. As shown in the schematic figure, its two ends are connected to two wires and it is hanging by those wires with its plane being vertical. The wires are connected to a capacitor with charge $Q$ through a switch. The coil is in a horizontal uniform magnetic field $B_o$ parallel to the plane of the coil. When the switch is closed, the capacitor gets discharged through the coil in a very short time. By the time the capacitor is discharged fully, magnitude of the angular momentum gained by the coil will be (assume that the discharge time is so short that the coil has hardly rotated during this time)

When water is filled carefully in a glass, one can fill it to a height $h$ above the rim of the glass due to the surface tension of water. To calculate $h$ just before water starts flowing, model the shape of the water above the rim as a disc of thickness $h$ having semicircular edges, as shown schematically in the figure. When the pressure of water at the bottom of this disc exceeds what can be withstood due to the surface tension, the water surface breaks near the rim and water starts flowing from there. If the density of water, its surface tension and the acceleration due to gravity are ${10}^3\mathrm{kg}{\mathrm{m}}^{-3},0.07\mathrm{N}{\mathrm{m}}^{-1}$ and $10\mathrm{m}{\mathrm{s}}^{-2}$ respectively, the value of $h$(in $\mathrm{mm}$)is ________.

A charged shell of radius $\mathrm{R}$ carries a total charge $\mathrm{Q}.$ Given $\mathrm{\Phi }$ as the flux of electric field through a closed cylindrical surface of height $\mathrm{h},$ radius $\mathrm{r}$ and with its center same as that of the shell. Here, center of the cylinder is a point on the axis of the cylinder which is equidistant from its top and bottom surfaces. Which of the following option(s) is/are correct? [ ${\in }_0$ is the permittivity of free space]

In the following circuit, the current through the resistor $R(=2\mathrm{\Omega })$ is $\mathrm{I}$ Amperes. The value of $\mathrm{I}\mathrm{}$ is

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\(\mathbf{X}\) and \(\mathbf{Y}\) are two volatile liquids with molar weights of \(10 \mathrm{~g} \mathrm{~mol}^{-1}\) and \(40 \mathrm{~g} \mathrm{~mol}^{-1}\) respectively. Two cotton plugs, one soaked in \(\mathbf{X}\) and the other soaked in \(\mathbf{Y}\), are simultaneously placed at the ends of a tube of length \(L=24 \mathrm{~cm}\), as shown in the figure. The tube is filled with an inert gas at \(1\) atmosphere pressure and a temperature of \(300 \mathrm{~K}\). Vapours of \(\mathbf{X}\) and \(\mathbf{Y}\) react to form a product which is first observed at a distance \(\mathbf{d} \mathrm{~cm}\) from the plug soaked in \(\mathbf{X}\). Take \(\mathbf{X}\) and \(\mathbf{Y}\) to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.



Question:

The experimental value of \(\mathbf{d}\) is found to be smaller than the estimate obtained using Graham's law. This is due to