Both \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) and \(\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}\) are diamagnetic. The hybridisations of nickel in these complexes, respectively, are

The total number of distinct naturally occurring amino acids obtained by complete acidic hydrolysis of the peptide shown below is

With respect to hypochlorite, chlorate and perchlorate ions, choose the correct statement(s).

For the following reaction scheme, percentage yields are given along the arrow:

\(\mathbf{x} g\) and \(\mathbf{y} g\) are mass of \(\mathbf{R}\) and \(\mathbf{U}\), respectively.
(Use: Molar mass (in \(\mathrm{g} \mathrm{mol}^{-1}\) ) of \(\mathrm{H}, \mathrm{C}\) and \(\mathrm{O}\) as 1,12 and 16 , respectively)
The value of $\mathrm{x}$ is ___.

The packing efficiency of the two-dimensional square unit cell shown below is

Paragraph I: An organic compound \(\mathrm{P}\) with molecular formula \(\mathrm{C}_5 \mathrm{H}_{18} \mathrm{O}_2\) decolorizes bromine water and also shows positive iodoform test. \(\mathrm{P}\) on ozonolysis followed by treatment with \(\mathrm{H}_2 \mathrm{O}_2\) gives \(\mathrm{Q}\) and \(\mathrm{R}\). While compound \(\mathrm{Q}\) shows positive iodoform test, compound \(\mathrm{R}\) does not give positive iodoform test. \(\mathrm{Q}\) and \(\mathrm{R}\) on oxidation with pyridinium chlorochromate (PCC) followed by heating give \(\mathrm{S}\) and \(\mathrm{T}\), respectively. Both \(\mathrm{S}\) and \(\mathrm{T}\) show positive iodoform test.
Complete copolymerization of 500 moles of \(\mathrm{Q}\) and 500 moles of \(\mathrm{R}\) gives one mole of a single acyclic copolymer \(\mathrm{U}\).
[Given, atomic mass: \(\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16\)]
Question: The molecular weight of \(\mathbf{U}\) is

The correct statement(s) pertaining to the adsorption of a gas on a solid surface is(are)

Some standard electrode potentials at $298 \mathrm{K}$ are given below: $\begin{array}{ll}{\mathrm{Pb}}^{2+}/\mathrm{Pb}& -0.13 \mathrm{V}\end{array}$ $\begin{array}{ll}{\mathrm{Ni}}^{2+}/\mathrm{Ni}& -0.24 \mathrm{V}\end{array}$ $\begin{array}{ll}{\mathrm{Cd}}^{2+}/\mathrm{Cd}& -0.40 \mathrm{V}\end{array}$ $\begin{array}{ll}{\mathrm{Fe}}^{2+}/\mathrm{Fe}& -0.44 \mathrm{V}\end{array}$ To a solution containing $0.001 \mathrm{M}$ of ${\mathbf{X}}^{2+}$ and $0.1 \mathrm{M}$ of ${\mathbf{Y}}^{2+}$, the metal rods $\mathbf{X}$ and $\mathbf{Y}$ are inserted $($at $298 \mathrm{K})$ and connected by a conducting wire. This resulted in dissolution of $\mathbf{X}$. The correct combination(s) of $\mathbf{X}$ and $\mathbf{Y}$, respectively, is(are) (Given: Gas constant, $\mathrm{R}=8.314 \mathrm{J}{ \mathrm{K}}^{-1}{ \mathrm{mol}}^{-1}$, Faraday constant, $\mathrm{F}=96500 \mathrm{C} {\mathrm{mol}}^{-1}$)

Let \(E\) and \(F\) be two independent events. The probability that exactly one of them occurs is \(11 / 25\) and the probability of none of them occurring is \(2 / 25\). If \(P(T)\) denotes the probability of occurrence of the event \(T\), then

Let the function \(g:(-\infty, \infty) \rightarrow\left(-\frac{\pi}{2}, \frac{\pi}{2}\right)\) be given by \(g(u)=2 \tan ^{-1}\left(e^u\right)-\frac{\pi}{2}\). Then, \(g\) is

Consider the hyperbola $\frac{x^2}{100}-\frac{y^2}{64}=1$ with foci at $S$ and $S_1$, where $S$ lies on the positive $x$-axis. Let $P$ be a point on the hyperbola, in the first quadrant. Let $\angle SP{S}_1=\alpha$, with $\alpha <\frac{\pi }{2}$. The straight line passing through the point $S$ and having the same slope as that of the tangent at $P$ to the hyperbola, intersects the straight line $S_{1}P$ at $P_1$. Let $\delta$ be the distance of $P$ from the straight line $S{P}_1$, and $\beta =S_{1}P$. Then the greatest integer less than or equal to $\frac{\beta \delta }{9}\sin \frac{\alpha }{2}$ is _____ .

A block of weight $100\mathrm{}\mathrm{N}$ is suspended by copper and steel wires of same cross-sectional area $0.5\mathrm{}\mathrm{c}{\mathrm{m}}^2$ and, length $\sqrt{3}\mathrm{}\mathrm{m}$ and $1\mathrm{}\mathrm{m},$ respectively. Their other ends are fixed on a ceiling as shown in figure. The angles subtended by copper and steel wires with ceiling are ${30}^{\mathrm{o}}$ and ${60}^{\mathrm{o}},$ respectively. If elongation in copper wire is $\left(\mathrm{\Delta }{\mathrm{l}}_{\mathrm{C}}\right)$ and elongation in steel wire is $\left(\mathrm{\Delta }{\mathrm{l}}_{\mathrm{S}}\right),$ then the ratio $\frac{\mathrm{\Delta }{\mathrm{l}}_{\mathrm{C}}}{\mathrm{\Delta }{\mathrm{l}}_{\mathrm{S}}}$ is _____.
[Young's modulus for copper and steel are $1\times {10}^{11}\mathrm{N}/{\mathrm{m}}^2$ and $2\times {10}^{11}\mathrm{N}/{\mathrm{m}}^2$ respectively]

For the following electrochemical cell at $\text{289 K,}$
\(\operatorname{Pt}( s ) \mid H _2(g, 1\) bar \() \mid H ^{+}( aq , 1 M ) \| M ^{4+}(\) aq. \(), M ^{2+}(\) aq. \() \mid \operatorname{Pt}( s )\)
${\mathrm{E}}_{\mathrm{c}\mathrm{e}\mathrm{l}\mathrm{l}}=0.092\mathrm{ }\mathrm{V}$ when $\frac{\left[{\mathrm{M}}^{2+}\left(\mathrm{a}\mathrm{q}.\right)\right]}{\left[{\mathrm{M}}^{4+}\left(\mathrm{a}\mathrm{q}.\right)\right]}={10}^{\mathrm{x}}$
Given: ${\mathrm{E}}_{{\mathrm{M}}^{4+}/{\mathrm{M}}^{2+}}^0=0.151\mathrm{ }\mathrm{V}\mathrm{ };2.303\frac{\mathrm{R}\mathrm{T}}{\mathrm{F}}=0.059$
The value of $\text{x}$ is -