Consider the kinetic data given in the following table for the reaction $\mathrm{A}+\mathrm{B}+\mathrm{C}\to$ Product.

Ex peri ment No.	\([\text A]\) \((\text{mol}\) \(\text{dm} ^{-3})\)	\([\text B]\) \((\text{mol}\) \(\text{dm} ^{-3})\)	\([\text C]\) \((\text{mol}\) \(\text{dm} ^{-3})\)	Rate of reaction \((\text{mol}\) \(\text{dm} ^{-3}\) \(\text s^{-1})\)
1	0.2	0.1	0.1	\(6.0 \times\) \(10^{-5}\)
2	0.2	0.2	0.1	\(6.0 \times \) \(10^{-5}\)
3	0.2	0.1	0.2	\(1.2 \times \) \(10^{-4}\)
4	0.3	0.1	0.1	\(9.0 \times \) \(10^{-5}\)

The rate of the reaction for $\left[\mathrm{A}\right]=0.15\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3},\mathrm{ }\left[\mathrm{B}\right]=0.25\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3}$ and $\left[\mathrm{C}\right]=0.15\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3}$ is found to be $\mathrm{Y}\times {10}^{-5}\mathrm{ }\mathrm{m}\mathrm{o}\mathrm{l}\mathrm{ }\mathrm{d}{\mathrm{m}}^{-3}{\mathrm{s}}^{-1}.$ The value of $\mathrm{Y}$ is __________

In allene \(\left(\mathrm{C}_{3} \mathrm{H}_{4}\right)\), the type(s) of hybridisation of the carbon atoms is (are):

Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction as shown in the given scheme.

Paragraph I: An organic compound \(\mathbf{P}\) with molecular formula \(\mathrm{C}_9 \mathrm{H}_{18} \mathrm{O}_2\) decolorizes bromine water and also shows positive iodoform test. \(\mathbf{P}\) on ozonolysis followed by treatment with \(\mathrm{H}_2 \mathrm{O}_2\) gives \(\mathbf{Q}\) and \(\mathbf{R}\). While compound \(\mathbf{Q}\) shows positive iodoform test, compound \(\mathbf{R}\) does not give positive iodoform test. \(\mathbf{Q}\) and \(\mathbf{R}\) on oxidation with pyridinium chlorochromate (PCC) followed by heating give \(\mathbf{S}\) and \(\mathbf{T}\), respectively. Both \(\mathbf{S}\) and \(\mathbf{T}\) show positive iodoform test.
Complete copolymerization of 500 moles of \(\mathbf{Q}\) and 500 moles of \(\mathbf{R}\) gives one mole of a single acyclic copolymer \(\mathbf{U}\).
[Given, atomic mass: \(\mathrm{H}=1, \mathrm{C}=12, \mathrm{O}=16\)]
Question: Sum of number of oxygen atoms in \(\mathbf{S}\) and \(\mathbf{T}\) is

Paragraph:
Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately \(6.023 \times 10^{23}\) ) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.
A \(4.0\) molar aqueous solution of \(\mathrm{NaCl}\) is prepared and \(500 \mathrm{~mL}\) of this solution is electrolysed. This leads to the evolution of chlorine gas at one of electrodes (atomic mass: \(\mathrm{Na}=23, \mathrm{Hg}=200 ; 1\) faraday \(=96500\) coulombs).
Question:
The total charge (coulombs) required for complete electrolysis is

The concentration of \(R\) in the reaction \(R \longrightarrow P\) was measured as a function of time and the following data is obtained :
\(\begin{array}{lllll}{[R] \text { (molar) }} & 1.0 & 0.75 & 0.40 & 0.10 \\ t \text { (min) } & 0.0 & 0.05 & 0.12 & 0.18\end{array}\)
The order of the reaction is

For a dilute solution containing \(2.5 \mathrm{~g}\) of a non-volatile non-electrolyte solute in \(100 \mathrm{~g}\) of water, the elevation in boiling point at 1 atm pressure is \(2^{\circ} \mathrm{C}\). Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure ( \(\mathrm{mm}\) of \(\mathrm{Hg}\) ) of the solution is (take \(K_{b}=0.76 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\) )

If the angles \(A, B\) and \(C\) of a triangle are in an arithmetic progression and if \(a, b\) and \(c\) denote the lengths of the sides opposite to \(A, B\) and \(C\) respectively, then the value of the expression \(\frac{a}{c} \sin 2 C+\frac{c}{a} \sin 2 A\) is

Let \(\mathbf{a}=-\hat{\mathbf{i}}-\hat{\mathbf{k}}, \mathbf{b}=-\hat{\mathbf{i}}+\hat{\mathbf{j}}\) and \(\mathbf{c}=\hat{\mathbf{i}}+2 \hat{\mathbf{j}}+3 \hat{\mathbf{k}}\) be three given vectors. If \(\mathbf{r}\) is a vector such that \(\mathbf{r} \times \mathbf{b}=\mathbf{c} \times \mathbf{b}\) and \(\mathbf{r} \cdot \mathbf{a}=0\), then the value of \(\mathbf{r} \cdot \mathbf{b}\) is

Let \(f: R \rightarrow R\) be a function such that \(f(x+y)=f(x)+f(y), \forall x, y \in R\). If \(f(x)\) is differentiable at \(x=0\), then

Total number of isomers, considering both structural and stereoisomers, of cyclic ethers with the molecular formula ${\mathrm{C}}_4{\mathrm{H}}_8\mathrm{O}$ is ________

An ideal gas in a thermally insulated vessel at internal pressure = ${\mathrm{P}}_1$ , volume = ${\mathrm{V}}_1$ and absolute temperature = ${\mathrm{T}}_1$ expands irreversibly against zero external pressure, as shown in the diagram. The final internal pressure, volume and absolute temperature of the gas are ${\mathrm{P}}_2$ , ${\mathrm{V}}_2$ and ${\mathrm{T}}_2$ , respectively. For this expansion,

Electrons with de-Broglie wavelength \(\lambda\) fall on the target in an X-ray tube. The cut-off wavelength of the emitted X-rays is