The concentration of \(R\) in the reaction \(R \longrightarrow P\) was measured as a function of time and the following data is obtained :
\(\begin{array}{lllll}{[R] \text { (molar) }} & 1.0 & 0.75 & 0.40 & 0.10 \\ t \text { (min) } & 0.0 & 0.05 & 0.12 & 0.18\end{array}\)
The order of the reaction is

Among the following, the coloured compound is

KI in acetone, undergoes S_N2 reaction with each of P, Q, R and S. The rates of the reaction vary as

Match the following

Column I	Column II
(A) \(CH _3- CHBr - CD _3\) on treatment with alc. KOH gives \(CH _2= CH - CD _3\) as a major product.	(P) E1 reaction
(B) \(Ph - CHBr - CH _3\) reacts faster than \(Ph - CHBr - CD _3\)	(Q) E2 reaction
(C) \(Ph - CH _2- CH _2 Br\) on treatment with \(C _2 H _5 OD / C _2 H _5 O ^{-}\)gives \(Ph - CD = CH _2\) as the major product	(R) El cb reaction
(D) \(PhCH _2 CH _2 Br\) and \(PhCH _2 CH _2 Br\) react with same rate	(S) First order reaction

\(2.5 \mathrm{~mL}\) of \(\frac{2}{5} \mathrm{M}\) weak monoacidic base \(\left(K_b=1 \times 10^{-12}\right.\) at \(\left.25^{\circ} \mathrm{C}\right)\) is titrated with \(\frac{2}{15}\) \(\mathrm{M} \mathrm{HCl}\) in water at \(25^{\circ} \mathrm{C}\). The concentration of \(\mathrm{H}^{+}\)at equivalence point is \(\left(K_w=1 \times 10^{-14}\right.\) at \(\left.25^{\circ} \mathrm{C}\right)\)

Match the extraction processes listed in column I with metals listed in column II.

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Thermal decomposition of gaseous \(\mathrm{X}_{2}\) to gaseous \(\mathrm{X}\) at \(298 \mathrm{~K}\) takes place according to the following equation:

\(\mathrm{X}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{X}(\mathrm{g})\)

The standard reaction Gibbs energy, \(\Delta_{r} G^{\circ}\), of this reaction is positive. At the start of the reaction, there is one mole of \(\mathrm{X}_{2}\) and no \(\mathrm{X}\). As the reaction proceeds, the number of moles of \(\mathrm{X}\) formed is given by \(\beta\). Thus, \(\beta_{\text {equilibrium }}\) is the number of moles of \(\mathrm{X}\) formed at equilibrium. The reaction is carried out at a constant total pressure of \(2\) bar. Consider the gases to behave ideally. (Given : \(R=0.083 \mathrm{~L}\) bar \(\mathrm{K}^{-1} \mathrm{~mol}^{-1}\) )

Question:
The INCORRECT statement among the following, for this reaction, is

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The hydrogen-like species \(\mathrm{Li}^{2+}\) is in a spherically symmetric state \(S_1\) with one radial node. Upon absorbing light the ion undergoes transition to a state \(S_2\). The state \(S_2\) has one radial node and its energy is equal to the ground state energy of the hydrogen atom.
Question:
The state \(S_1\) is

A number is chosen at random from the set $\left\{1,2,3,\dots ,2000\right\}$. Let $p$ be the probability that the chosen number is a multiple of 3 or $7$. Then the value of $500p$ is ____.

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Tangents are drawn from the point \(P(3,4)\) to the ellipse \(\frac{x^2}{9}+\frac{y^2}{4}=1\) touching the ellipse at points \(A\) and \(B\).Question:
The orthocentre of the triangle \(P A B\) is

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Given that for each \(a \in(0,1)\),

\(\lim _{h \rightarrow 0^{+}} \int_{h}^{1-h} t^{-a}(1-t)^{a-1} d t\)

exists. Let this limit be \(g(a)\). In addition, it is given that the function \(g(a)\) is differentiable on \((0,1)\).


Question:

The value of \(g\left(\frac{1}{2}\right)\) is

Let $\mathrm{y}\left(\mathrm{x}\right)$ be a solution of the differential equation $\left(1+{\mathrm{e}}^{\mathrm{x}}\right)\mathrm{ }{\mathrm{y}}^{\mathrm{\prime }}+\mathrm{y}{\mathrm{e}}^{\mathrm{x}}=1.$ If $\mathrm{y}\left(0\right)=2$ , then which of the following statements is (are) true?

Statement I A block of mass \(m\) starts moving on a rough horizontal surface with a velocity \(v\). It stops due to friction between the block and the surface after moving through a certain distance. The surface is now tilted to an angle of \(30^{\circ}\) with the horizontal and the same block is made to go up on the surface with the same initial velocity \(v\). The decrease in the mechanical energy in the second situation is smaller than that in the first situation.
Statement II The coefficient of friction between the block and the surface decreases with the increase in the angle of inclination.