JEE Advanced · Chemistry · 25. Alcohols, Phenols & Ethers
A trinitro compound, -tris-(-nitrophenyl) benzene, on complete reaction with an excess of gives a major product, which on treatment with an excess of at provides as the product. , upon treatment with excess of at room temperature, gives the product . Bromination of in aqueous medium furnishes the product . The compound upon treatment with an excess of phenol under basic conditions gives the product . The molar mass difference between compounds and is and between compounds and is .
The number of heteroatoms present in one molecule of \(R\) is [Use: Molar mass (in \(\text{g mol} -1\) ): \(H =1,\) \(C =12, N=14, O =16,\) \(Br =80, Cl =35.5\) Atoms other than C and H are considered as heteroatoms]
- A 9
- B 5
- C 1
- D 10
Answer & Solution
Correct Answer
(A) 9
Step-by-step Solution
Detailed explanation
Nitrobenzene part converts to aniline part using . Aniline forms diazonium salt with nitrous acid and hydrogen chloride. Diazonium salt forms phenol with warm water.Phenol forms poly substituted bromo compound with bromine water.



The hetero atoms present the product are 6 bromine atoms and 3 oxygen atoms. Number of Hetero atoms in is .



The hetero atoms present the product are 6 bromine atoms and 3 oxygen atoms. Number of Hetero atoms in is .
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