Among \(\left[ I _3\right]^{+},\left[ SiO _4\right]^{4-}, SO _2 Cl _2, XeF _2, SF _4, ClF _3,\) \(Ni ( CO )_4, XeO _2 F_2,\left[ PtCl _4\right]^{2-}, XeF _4\), and \(SOCl _2\), the total number of species having \(sp ^3\) hybridised central atom is

Consider a reaction \(A+R \rightarrow\) Product. The rate of this reaction is measured to be \(k[A][R]\). At the start of the reaction, the concentration of \(R,[R]_0\), is 10 -times the concentration of \(A,[A]_0\). The reaction can be considered to be a pseudo first order reaction with assumption that \(k[R]=k^{\prime}\) is constant. Due to this assumption, the relative error (in \%) in the rate when this reaction is \(40 \%\) complete, is _______
[ \(k\) and \(k^{\prime}\) represent corresponding rate constants]

The solubility of barium iodate in an aqueous solution prepared by mixing 200 mL of 0.010 M barium nitrate with 100 mL of 0.10 M sodium iodate is \(\boldsymbol{X} \times 10^{-6} \mathrm{~mol} \mathrm{dm}^{-3}\). The value of \(\boldsymbol{X}\) is \(\qquad\) .
Use: Solubility product constant \(\left(K_{\mathrm{sp}}\right)\) of barium iodate \(=1.58 \times 10^{-9}\)

The shape of \(\mathrm{XeO}_{2} \mathrm{~F}_{2}\) molecule is

The correct statement(s) related to oxoacids of phosphorous is(are)

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Reimer-Tiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicylaldehydes as depicted below.

Question :
The electrophile in this reaction is

The bond energy (in \(\mathrm{kcal} \mathrm{mol}^{-1}\) ) of \(\mathrm{C}-\mathrm{C}\) single bond is approximately

Let $f:\left(0, \pi \right)\to \mathbb{R}$ be a twice differentiable function such that $\underset{t\to x}{\lim }\frac{f\left(x\right)\sin t-f\left(t\right)\sin x}{t-x}={\sin }^{2}x$ for all $x\in \left(0, \pi \right)$. If $f\left(\frac{\pi }{6}\right)=-\frac{\pi }{12}$, then which of the following statement(s) is (are) TRUE ?

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Scientists are working hard to develop nuclear fusion reactor. Nuclei of heavy hydrogen, \({ }_1^2 \mathrm{H}\) known as deuteron and denoted by \(D\) can be thought of as a candidate for fusion reactor. The \(D\) - \(D\) reaction is \({ }_1^2 \mathrm{H}+{ }_1^2 \mathrm{H} \rightarrow{ }_2^3 \mathrm{He}+n+\) energy. In the core of fusion reactor. A gas of heavy hydrogen is fully ionized into deuteron nuclei and electrons. This collection of \({ }_1^4 \mathrm{H}\) nuclei and electrons is known as plasma. The nuclei move randomly in the reactor core and occasionally come close enough for nuclear fusion to take place. Usually, the temperatures in the reactor core are too high and no material wall can be used to confine the plasma. Special techniques are used which confine the plasma for a time \(t_0\) before the particles fly away from the core. If n is the density (number/volume) of deutrons, the product t \(_0\) is called Lawson number. In one of the criteria, \(a\) reactor is termed successful if Lawson number is greater than \(5 \times 10^{14} \mathrm{scm}^{-3}\).
It may be helpful to use the following : Boltzmann constant \(k=8.6 \times 10^{-5} \mathrm{eV} / \mathrm{K}\); \(\frac{e^2}{4 \pi \varepsilon_0}=1.44 \times 10^{-9} \mathrm{eVm}\)
Question:
Assume that two deuteron nuclei in the core of fusion reactor at temperature \(T\) are moving towards each other, each with kinetic energy \(1.5 \mathrm{kT}\), when the separation between them is large enough to neglect Coulomb potential energy. Also neglect any interaction from other particles in the core. The minimum temperature \(T\) required for them to reach a separation of \(4 \times 10^{-15} \mathrm{~m}\) is in the range

Let \(f:[-1,2] \rightarrow[0, \infty)\) be a continuous function such that \(f(x)=f(1-x)\) for all \(x \in[-1,2]\). Let \(R_1=\int_{-1}^2 x f(x) d x\) and \(R_2\) be the area of the region bounded by \(y=f(x), x=-1, x=2\) and the \(X\)-axis. Then,

Two lines ${\text{L}}_1\text{ : }\text{x}=5\text{,}\frac{\text{y}}{3-\alpha }=\frac{\text{z}}{-2}$ and ${\text{L}}_2\text{ : }\text{x}=\alpha \text{,}\frac{\text{y}}{-1}=\frac{\text{z}}{2-\alpha }$ are coplanar. Then $\alpha$ can take value(s)

A transparent slab of thickness d has a refractive index n (z) that increases with z. Here z is the vertical distance inside the slab, measured from the top. The slab is placed between two media with uniform refractive indices $n_{1}and{n}_2\left(>n_1\right),$ as shown in the figure. A ray of light is incident with angle ${\theta }_i$ from medium 1 and emerges in medium 2 with refraction angle ${\theta }_f$ with a lateral displacement $\mathcal{l}$ . Which of the following statement(s) is (are) true?

In the following reactions, P, Q, R and S are the major products.

The correct statement(s) about P, Q, R and S is(are)