Choose the reaction(s) from the following options, for which the standard enthalpy of reaction is equal to the standard enthalpy of formation.

For the first order reaction \(2 \mathrm{~N}_2 \mathrm{O}_5(\mathrm{~g}) \longrightarrow 4 \mathrm{NO}_2(g)+\mathrm{O}_2(g)\)

The reaction of ${\mathrm{HClO}}_3$ with $\mathrm{HCl}$ gives a paramagnetic gas, which upon reaction with ${\mathrm{O}}_3$ produces

In the following carbocation, \(\mathrm{H} / \mathrm{CH}_3\) that is most likely to migrate to the positively charged carbon is

The increasing order of atomic radii of the following group $13$ elements is

Consider the following compounds in the liquid form:
\(O_2, HF, H_2 O, NH_3, H_2 O_2, CCl_4, CHCl_3,\) \(C_6 H_6, C_6 H_5 Cl .\)
When a charged comb is brought near their flowing stream, how many of them show deflection as per the following figure?

Correct option(s) for the following sequence of reactions is(are)

An ideal gas is undergoing a cyclic thermodynamic process in different ways as shown in the corresponding P-V diagrams in column 3 of the table. Consider only the path from state 1 to state 2. W denotes the corresponding work done on the system. The equations and plots in the table have standard notations as used in thermodynamic process. Here $\gamma$ is the ratio of heat capacities at constant pressure and constant volume. The number of moles in the gas is n.

Column – 1	Column – 2	Column – 3
(I) \(W_{1 \rightarrow 2}=\frac{1}{\gamma-1}\) \(\left(P_2 V_2-P_1 V_1\right)\)	(i) Isothermal	(P)
(II) \(W_{1 \rightarrow 2}=\) \(-P V_2+P V_1\)	(ii) Isochoric	(Q)
(III) \(W_{1 \rightarrow 2}=0\)	(iii) Isobaric	(R)
(IV) \(W_{1 \rightarrow 2}=\) \(-n R T \ln \left(\frac{V_2}{V_1}\right)\)	(iv) Adiabatic	(S)

Which of the following options is the only correct representation of the process $∆U=∆Q-P∆V$?

Paragraph :
A spray gun is shown in the figure where a piston pushes air out of a nozzle. A thin tube of uniform cross section is connected to the nozzle. The other end of the tube is in a small liquid container. As the piston pushes air through the nozzle, the liquid from the container rises into the nozzle and is sprayed out. For the spray gun shown, the radii of the piston and the nozzle are \(20 \mathrm{~mm}\) and \(1 \mathrm{~mm}\), respectively. The upper end of the container is open to the atmosphere.

Question :
If the piston is pushed at a speed of \(5 \mathrm{~mms}^{-1}\), the air comes out of the nozzle with a speed of

Let \(\mathbb{R}\) denote the set of all real numbers. For a real number \(x\), let \([x]\) denote the greatest integer less than or equal to \(x\). Let \(n\) denote a natural number.
Match each entry in List-I to the correct entry in List-II and choose the correct option.

	LIST - I		LIST - II
(P)	The minimum value of \(n\) for which the function \(f(x)=\left[\frac{10 x^3-45 x^2+60 x+35}{n}\right]\) is continuous on the interval \([1,2]\),is	(1)	8
(Q)	The minimum value of \(n\) for which \(g(x)=\left(2 n^2-13 n-15\right)\left(x^3+3 x\right),x \in \mathbb{R}\),is an increasing function on \(\mathbb{R}\),is	(2)	9
(R)	The smallest natural number \(n\) which is greater than 5,such that \(x=3\) is a point of local minima of \(h(x)=\left(x^2-9\right)^{\mathrm{n}}\left(x^2+2 x+3\right)\),is	(3)	5
(S)	Number of \(x_0 \in \mathbb{R}\) such that \(l(x)=\sum_{k=0}^4\left(\sin |x-k|+\cos \left|x-k+\frac{1}{2}\right|\right),x \in \mathbb{R}\),is NOT differentiable at \(x_0\),is	(4)	6
		(5)	10

Consider the lines \(L_{1}\) and \(L_{2}\) defined by
\[
L_{1}: x \sqrt{2}+y-1=0 \text { and } L_{2}: x \sqrt{2}-y+1=0
\]
For a fixed constant \(\lambda\), let \(C\) be the locus of a point \(P\) such that the product of the distance of \(P\) from \(L_{1}\) and the distance of \(P\) from \(L_{2}\) is \(\lambda^{2}\). The line \(y=2 x+1\) meets \(C\) at two points \(R\) and \(S\), where the distance between \(R\) and \(S\) is \(\sqrt{270}\).
Let the perpendicular bisector of \(R S\) meet \(C\) at two distinct points \(R^{\prime}\) and \(S^{\prime}\). Let \(D\) be the square of the distance between \(R^{\prime}\) and \(S^{\prime}\).
The value of $D$ is

A circle S passes through the point (0, 1) and is orthogonal to the circles ${\left(x-1\right)}^2+y^2=16$ and $x^2+y^2=1$. Then

An annular disk of mass $M$, inner radius $a$ and outer radius $b$ is placed on a horizontal surface with coefficient of friction $\mu$, as shown in the figure. At some time, an impulse $J_0\stackrel{\wedge }{x}$ is applied at a height $h$ above the center of the disk. If $h=h_m$ then the disk rolls without slipping along the $x$-axis. Which of the following statement(s) is(are) correct?