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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

निम्नलिखित संकुलों के प्रचक्रण-मात्र चुम्बकीय आघूर्णों का सही क्रम है : \((I)\) \(\left[ Cr \left( H _{2} O \right)_{6}\right] Br _{2}\) \((II)\) \(Na _{4}\left[ Fe ( CN )_{6}\right]\) \((III)\) \(Na _{3}\left[ Fe \left( C _{2} O _{4}\right)_{3}\right]\left(\Delta_{0}> P \right)\) \((IV)\) \(\left( Et _{4} N \right)_{2}\left[ CoCl _{4}\right]\)

  1. A \((III) > (I) > (II) > (IV)\)
  2. B \((I) > (IV) > (III) > (II)\)
  3. C \((\mathrm{II}) \approx(\mathrm{I})>(\mathrm{IV})>(\mathrm{III})\)
  4. D \((\mathrm{III})>(\mathrm{I})>(\mathrm{IV})>(\mathrm{II})\)
Verified Solution

Answer & Solution

Correct Answer

(B) \((I) > (IV) > (III) > (II)\)

Step-by-step Solution

Detailed explanation

\((I)\;\;\left[\mathrm{Cr}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}\) \(\mathrm{Cr}^{+2} \Rightarrow[\mathrm{Ar}] 3 \mathrm{d}^{4}\) \(\mathrm{H}_{2} \mathrm{O} \rightarrow\) Weak field ligand \(\text { Unpaired } \mathrm{e}^{-}=4\)…
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