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JEE Mains · Physics · STD 11 - Kinetic theory of gases
  • JEE Mains 2020
  • Medium
  • MCQ

Consider two ideal diatomic gases \(\mathrm{A}\) and \(\mathrm{B}\) at some temperature \(T\). Molecules of the gas \(A\) are rigid, and have a mass \(m\). Molecules of the gas \(\mathrm{B}\) have an additional vibrational mode, and have a mass \(\frac{\mathrm{m}}{4} .\) The ratio of the specific heats \((\mathrm{C}_{\mathrm{v}}^{\mathrm{A}}\) and \(\mathrm{C}_{\mathrm{v}}^{\mathrm{B}})\) of gas \(\mathrm{A}\) and \(\mathrm{B}\), respectively is

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(B) \(5:7\)

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Detailed explanation

Degree of freedom of a diatomic molecule if vibration is absent \(=5\)

Degree of freedom of a diatomic molecule if vibration is present \(=7\)

\(\therefore C_{v}^{A}=\frac{f_{A}}{2} R=\frac{5}{2} R\) and \(C_{v}^{B}=\frac{f_{B}}{2} R=\frac{7}{2} R\)

\(\therefore \quad \frac{C_{\mathrm{v}}^{\mathrm{A}}}{C_{\mathrm{v}}^{\mathrm{B}}}=\frac{5}{7}\)

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