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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

' \(X\) ' is the number of electrons in \(t_{2 g}\) orbitals of the most stable complex ion among \(\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{3+}\), \(\left[\mathrm{Fe}\left(\mathrm{Cl}_6\right)\right]^{3-},\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}\) and \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}\). The nature of oxide of vanadium of the type \(\mathrm{V}_2 \mathrm{O}_{\mathrm{X}}\) is _______.

  1. A Acidic
  2. B Neutral
  3. C Basic
  4. D Amphoteric
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Answer & Solution

Correct Answer

(D) Amphoteric

Step-by-step Solution

Detailed explanation

Most stable is \(\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}\) due to Chelation effect. \(\mathrm{V}_2 \mathrm{O}_5\) is amphoteric.
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