JEE Mains · Chemistry · STD 12 - 8.2 Carboxylic acids and their derivative
Which one of the following reactions will not form acetaldehyde ?
- A \(CH _{3} CH _{2} OH\) \(\xrightarrow[{573\,\,K}]{{Cu}}\)
- B \(CH _{3} CN \frac{( i ) DBAL - H }{( i ) H _{2} O }\) \(\xrightarrow[{(ii)\,{H_2}o}]{{{\text{(i) DIBAL - H}}}}\)
- C \(CH _{2}= CH _{2}+ O _{2}\) \(\xrightarrow[{{H_2}O}]{{Pd(II)/Cu(II)}}\)
- D \(CH _{3} CH _{2} OH\) \(\xrightarrow{{Cr{O_3} - {H_2}S{O_4}}}\)
Answer & Solution
Correct Answer
(D) \(CH _{3} CH _{2} OH\) \(\xrightarrow{{Cr{O_3} - {H_2}S{O_4}}}\)
Step-by-step Solution
Detailed explanation
\(C{H_3} - C{H_2} - OH\xrightarrow[{{\text{Strong oxidising agent}}}]{{Cr{O_3} \cdot {H_2}S{O_4}}}\begin{array}{*{20}{c}} O \\ {||} \\ {C{H_3} - C - OH} \\ {{\text{(Carboxylic acid is formed by complete oxidation )}}} \end{array}\)
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