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JEE Mains · Chemistry · STD 11 - 8.1. Organic chemistry Nomenclature of organic compounds

Which of the following has the shortest \(C-Cl\) bond?

  1. A \(Cl-CH=CH-OCH_3\)
  2. B \(Cl-CH=CH-CH_3\)
  3. C \(Cl-CH=CH_2\)
  4. D \(Cl-CH=CH-NO_2\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(Cl-CH=CH-NO_2\)

Step-by-step Solution

Detailed explanation

Due to \(- M\) effect of \(-\mathrm{NO}_{2}\) and \(+\mathrm{M}\) effect of \(\mathrm{Cl}\) more \(D.B.\) character between \(\mathrm{C}-\mathrm{Cl}\) bond. So shortest bond length.
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