JEE Mains · Chemistry · STD 12 - 4. d and f- block elements
The spin-only magnetic moment value of \(M ^{3+}\) ion (in gaseous state) from the pairs \(Cr ^{3+} / Cr ^{2+}\), \(Mn ^{3+} / Mn ^{2}, Fe ^{3+} / Fe ^{2+}\) and \(Co ^{3+} / Co ^{2+}\) that has negative standard electrode potential, is \(B.M...........\) [Nearest integer]
- A \(4\)
- B \(2\)
- C \(3\)
- D \(1\)
Answer & Solution
Correct Answer
(A) \(4\)
Step-by-step Solution
Detailed explanation
\(\left. E _{ Cr ^{+3}}^{0}\right|_{ Cr ^{+2}}=-0.41\,V\) \({\left[ Cr ^{+3}\right]=4 s ^{0} 3 d ^{3} }\) \(\mu=\sqrt{ n ( n +2)}\,B.M\) \(=\sqrt{15}\) B.M \(\sim 4\,B.M\)
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