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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

The spin-only magnetic moment value of an octahedral complex among \(CoCl _{3} \cdot 4 NH _{3}\), \(NiCl _{2} \cdot 6 H _{2} O\) and \(PtCl _{4} \cdot 2 HCl\), which upon reaction with excess of \(AgNO _{3}\) gives \(2\, moles\) of \(AgCl\) is \(....\,B.M.\) (Nearest Integer)

  1. A \(3\)
  2. B \(30\)
  3. C \(12\)
  4. D \(1\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(3\)

Step-by-step Solution

Detailed explanation

\(CoCl _{3} \cdot 4 NH _{3} \rightarrow\left[ Co \left( NH _{3}\right)_{4} Cl _{2}\right] Cl\) \(NiCl _{2} \cdot 6 H _{2} O \rightarrow\left[ Ni \left( H _{2} O \right)_{6}\right] Cl _{2}\) \(PtCl _{4} \cdot 2 HCl \rightarrow H _{2}\left[ PtCl _{6}\right]\)…
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