JEE Mains · Chemistry · STD 12 - 6. Haloalkanes and Haloarenes
The correct order of reactivity of \(CH_{3}Br\) in methanol with the following nucleophiles is:
\(F^{-}, I^{-}, C_{2}H_{5}O^{-}\) and \(C_{6}H_{5}O^{-}\)
- A \(I^{-}>C_{6}H_{5}O^{-}>F^{-}>C_{2}H_{5}O^{-}\)
- B \(I^{-}>C_{2}H_{5}O^{-}>C_{6}H_{5}O^{-}>F^{-}\)
- C \(I^{-}>C_{2}H_{5}O^{-}>F^{-}>C_{6}H_{5}O^{-}\)
- D \(I^{-}>F^{-}>C_{6}H_{5}O^{-}>C_{2}H_{5}O^{-}\)
Answer & Solution
Correct Answer
(B) \(I^{-}>C_{2}H_{5}O^{-}>C_{6}H_{5}O^{-}>F^{-}\)
Step-by-step Solution
Detailed explanation
Order of nucleophilicity: \(I ^{\ominus}> C _2 H _5 O ^{\ominus}> PhO ^{\ominus}> F ^{\ominus}\)
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