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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

The complex cation which has two isomers is:

  1. A \(\left[ Co \left( H _2 O \right)_6\right]^{3+}\)
  2. B \(\left[ Co \left( NH _3\right)_5 Cl \right]^{2+}\)
  3. C \(\left[ Co \left( NH _3\right)_5 NO _2\right]^{2+}\)
  4. D \(\left[ Co \left( NH _3\right)_5 Cl \right]^{+}\)
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Answer & Solution

Correct Answer

(C) \(\left[ Co \left( NH _3\right)_5 NO _2\right]^{2+}\)

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Detailed explanation

\(\left(\left[ Co \left( NH _3\right)_5 NO _2\right]^{2+}\right.\) Two linkage isomers possible \(NO _2 \rightarrow\) Ambidentate ligand
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