JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Number of complexes which show optical isomerism among the following is _______. \(\operatorname{cis}-\left[\mathrm{Cr}(\mathrm{ox})_2 \mathrm{Cl}_2\right]^{3-},\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}\) \(\operatorname{cis}-\left[\mathrm{Pt}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{2+}, \text { cis }-\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{+}\) \(\text {trans }-\left[\mathrm{Pt}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{2+}, \text { trans }-\left[\mathrm{Cr}(\mathrm{ox})_2 \mathrm{Cl}_2\right]^{3-}\)
- A \(4\)
- B \(5\)
- C \(6\)
- D \(7\)
Answer & Solution
Correct Answer
(A) \(4\)
Step-by-step Solution
Detailed explanation
cis \(-\left[\mathrm{Cr}(\mathrm{ox})_2 \mathrm{Cl}_2\right]^{3-} \rightarrow\) can show optical isomerism (no \(POS\) & \(COS\)) \(\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+} \rightarrow\) can show (no \(POS\) & \(COS\)) cis…
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