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JEE Mains · Chemistry · STD 11 - 8.2 Organic chemistry isomerism

n-Butane on monochlorination under photochemical condition gives an optically active compound "P". "P" on further chlorination gives dichloro compounds. The number of dichloro compounds obtained (ignore stereoisomers) is:

  1. A \(3\)
  2. B \(4\)
  3. C \(5\)
  4. D \(6\)
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Answer & Solution

Correct Answer

(B) \(4\)

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Detailed explanation

The structure of n-butane is \(CH_3-CH_2-CH_2-CH_3\). Monochlorination of n-butane gives two structural isomers: 1-chlorobutane and 2-chlorobutane. Among these, 2-chlorobutane (\(CH_3-CH_2-C^{*}HCl-CH_3\)) contains a chiral carbon atom and is optically active. Thus, the…
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