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JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry

Match the List - I with List - II
List - I
(Isothermal process for ideal gas system)
List - II
Work done \(\left(V_f>V_i\right)\)
A. Reversible expansionI. w = 0
B. Free expansionII. \(w =-n R T \ln \frac{V_{ f }}{ V _{ i }}\)
C. Irreversible expansionIII. \(w =- p _{ ex }\left( V _{ f }- V _{ i }\right)\)
D. Irreversible compressionIV. \(w =- p _{ ex }\left( V _{ i }- V _{ i }\right)\)
Choose the correct answer from the options given below :

  1. A A-IV, B-I, C-III, D-II
  2. B A-IV, B-II, C-III, D-I
  3. C A-I, B-III, C-II, D-IV
  4. D A-II, B-I, C-III, D-IV
Verified Solution

Answer & Solution

Correct Answer

(D) A-II, B-I, C-III, D-IV

Step-by-step Solution

Detailed explanation

(A) \(W _{ Rev .}=-\int P _{ gas } dV\) \(W _{\text {Rev. Isot. Exp. }}=- nRT \ln \left[\frac{ V _{ f }}{ V _{ i }}\right]\) (A) → (II) (B) Free expansion \(W _{ irrev. }=- P _{ ext } \Delta V\) \(P _{ ext }=0\) \(W =0\) \(( B ) \rightarrow( I )\) (C) Irreversible expansion…
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