JEE Mains · Chemistry · STD 11 - 5. Thermodynamics and thermochemistry
Match the List - I with List - II
| List - I (Isothermal process for ideal gas system) | List - II Work done \(\left(V_f>V_i\right)\) |
| A. Reversible expansion | I. w = 0 |
| B. Free expansion | II. \(w =-n R T \ln \frac{V_{ f }}{ V _{ i }}\) |
| C. Irreversible expansion | III. \(w =- p _{ ex }\left( V _{ f }- V _{ i }\right)\) |
| D. Irreversible compression | IV. \(w =- p _{ ex }\left( V _{ i }- V _{ i }\right)\) |
- A A-IV, B-I, C-III, D-II
- B A-IV, B-II, C-III, D-I
- C A-I, B-III, C-II, D-IV
- D A-II, B-I, C-III, D-IV
Answer & Solution
Correct Answer
(D) A-II, B-I, C-III, D-IV
Step-by-step Solution
Detailed explanation
(A) \(W _{ Rev .}=-\int P _{ gas } dV\) \(W _{\text {Rev. Isot. Exp. }}=- nRT \ln \left[\frac{ V _{ f }}{ V _{ i }}\right]\) (A) → (II) (B) Free expansion \(W _{ irrev. }=- P _{ ext } \Delta V\) \(P _{ ext }=0\) \(W =0\) \(( B ) \rightarrow( I )\) (C) Irreversible expansion…
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