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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Match the LIST-I with LIST-II
List-I
Electronic configuration of tetrahedral metal ion
List-II
Crystal Field Stabilization Energy (\(\Delta_t\))
A. \(d^2\)I. \(-0.6\)
B. \(d^4\)II. \(-0.8\)
C. \(d^6\)III. \(-1.2\)
D. \(d^8\)IV. \(-0.4\)

Choose the correct answer from the options given below:

  1. A A-III, B-IV, C-II, D-I
  2. B A-III, B-I, C-IV, D-II
  3. C A-III, B-IV, C-I, D-II
  4. D A-II, B-I, C-IV, D-III
Verified Solution

Answer & Solution

Correct Answer

(C) A-III, B-IV, C-I, D-II

Step-by-step Solution

Detailed explanation

In a tetrahedral crystal field, the d-orbitals split into a lower energy \(e\) set and a higher energy \(t_2\) set. The energy of an electron in the \(e\) orbital is \(-0.6 \Delta_t\) and in the \(t_2\) orbital is \(+0.4 \Delta_t\). Since \(\Delta_t\) is generally small,…
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