JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Match the LIST-I with LIST-II
| List-I Electronic configuration of tetrahedral metal ion | List-II Crystal Field Stabilization Energy (\(\Delta_t\)) |
|---|---|
| A. \(d^2\) | I. \(-0.6\) |
| B. \(d^4\) | II. \(-0.8\) |
| C. \(d^6\) | III. \(-1.2\) |
| D. \(d^8\) | IV. \(-0.4\) |
Choose the correct answer from the options given below:
- A A-III, B-IV, C-II, D-I
- B A-III, B-I, C-IV, D-II
- C A-III, B-IV, C-I, D-II
- D A-II, B-I, C-IV, D-III
Answer & Solution
Correct Answer
(C) A-III, B-IV, C-I, D-II
Step-by-step Solution
Detailed explanation
In a tetrahedral crystal field, the d-orbitals split into a lower energy \(e\) set and a higher energy \(t_2\) set. The energy of an electron in the \(e\) orbital is \(-0.6 \Delta_t\) and in the \(t_2\) orbital is \(+0.4 \Delta_t\). Since \(\Delta_t\) is generally small,…
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