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JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry

Match List-I with List-II
List - I
(Complex)
List - II (Primary valency and Secondary valency)
(A)[Co(en)2Cl2]Cl(I)36
(B)[Pt(NH3)2Cl(NO2)](II)34
(C)Hg[Co(SCN)4](III)26
(D)[Mg(EDTA)]2-(IV)24

Choose the correct answer from the options given below :

  1. A (A)-(III), (B)-(I), (C)-(II), (D)-(IV)
  2. B (A)-(I), (B)-(IV), (C)-(II), (D)-(III)
  3. C (A)-(I), (B)-(III), (C)-(II), (D)-(IV)
  4. D (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
Verified Solution

Answer & Solution

Correct Answer

(B) (A)-(I), (B)-(IV), (C)-(II), (D)-(III)

Step-by-step Solution

Detailed explanation

Primary valency \(=\) Oxidation state Secondary valency \(=\) Co-ordination number Complex Primary Valency Secondary Valency (A) [Co(en)2Cl2]Cl 3 6 (B) [Pt(NH3)2Cl(NO2)] 2 4 (C) Hg[Co(SCN)4] 3 4 (D) [Mg(EDTA)]2- 2 6
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