JEE Mains · Chemistry · STD 12 - 8.2 Carboxylic acids and their derivative
Match list \(- I\) and List \(- II.\)
| List \(-I\) | List \(-II\) | ||
| \((a)\) | \(\begin{array}{*{20}{c}} {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ {R - C - Cl \to R - CHO} \end{array}\) | \((i)\) | \(Br _{2} / NaOH\) |
| \((b)\) | \(\begin{array}{*{20}{c}} {R - C{H_2} - COOH \to R - CH - COOH} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|} \\ {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,Cl} \end{array}\) | \((ii)\) | \(H _{2} / Pd - BaSO _{4}\) |
| \((c)\) | \(\begin{array}{*{20}{c}} {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ {R - C - N{H_2} \to R - N{H_2}} \end{array}\) | \((iii)\) | \(Zn ( Hg ) /\) Conc. \(HCl\) |
| \((d)\) | \(\begin{array}{*{20}{c}} {O\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ {||\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ {R - C - C{H_3} \to R - C{H_2} - C{H_3}} \end{array}\) | \((iv)\) | \(Cl _{2}\) / Red \(P , H _{2} O\) |
- A \((a)-(ii), (b)-(i), (c)-(iv), (d)-(iii)\)
- B \((a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)\)
- C \((a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)\)
- D \((a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)\)
Answer & Solution
Correct Answer
(C) \((a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)\)
Step-by-step Solution
Detailed explanation
Match list\(-I\) And list\(-II\) \((a)\) \(\begin{array}{*{20}{c}} O \\ {||} \\ {R - C - Cl} \end{array}\xrightarrow[{Pd - BaS{O_4}}]{{{H_2}}}\begin{array}{*{20}{c}} {\,\,\,\,\,\,\,O} \\ {\,\,\,\,\,\,\,\,||} \\ {R{\text{ }} - {\text{ }}CH} \end{array}\) \((a)-(ii)\) Rosenmund…
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