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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

\(KMnO _4\) is titrated with ferrous ammonium sulphate hexahydrate in presence of dilute \(H _2 SO _4\). Number of water molecules produced for \(2\) molecules of \(KMnO _4\) is \(..........\).

  1. A \(67\)
  2. B \(65\)
  3. C \(68\)
  4. D \(66\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(68\)

Step-by-step Solution

Detailed explanation

By balancing the redox reaction we get \(10\left[ FeSO _4 \cdot\left( NH _4\right)_2 SO _4 \cdot 6 H _2 O \right]+2 KMnO _4+8 H _2 SO _4\) \(\downarrow\) \(5 Fe _2\left( SO _4\right)_3+2 MnSO _4+10\left( NH _4\right)_2 SO _4+ K _2 SO _4+68 H _2 O\)