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JEE Mains · Chemistry · STD 12 - 4. d and f- block elements

In basic medium \(CrO _{4}^{2-}\) oxidises \(S _{2} O _{3}^{2-}\) to form \(SO _{4}^{2-}\) and itself changes into \(Cr ( OH )_{4}^{-}\). The volume of \(0.154\, M CrO _{4}^{2-}\) required to react with \(40\, mL\) of \(0.25\, M S _{2} O _{3}^{2-}\) is ........... \(mL\) (Rounded-off to the nearest integer)

  1. A \(170\)
  2. B \(173\)
  3. C \(181\)
  4. D \(141\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(173\)

Step-by-step Solution

Detailed explanation

\(gm\) equi. of \(CrO _{4}^{2-}= S _{2} O _{3}^{2-}\) \(0.154 \times 3 \times v =0.25 \times 40 \times 8\) \(v =173.16=173 \,ml\)
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