JEE Mains · Chemistry · STD 12 - 5. Co-ordination chemistry
Identify the homoleptic complex(es) that is/are low spin.
(A) \(\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right]^{2-}\)
(B) \(\left[\mathrm{CoF}_6\right]^{3-}\)
(C) \(\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}\)
(D) \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}\)
(E) \(\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\)
Choose the correct answer from the options given below :
- A (C) only
- B (C) and (D) only
- C (A) and (C) only
- D (B) and (E) only
Answer & Solution
Correct Answer
(B) (C) and (D) only
Step-by-step Solution
Detailed explanation
(A) \(\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right]^{-2} \rightarrow\) Heteroleptic, \(\mathrm{Fe}^{+2}, 3 \mathrm{~d}^6\), \(\mathrm{t}_{2 \mathrm{~g}}{ }^6 \mathrm{e}_{\mathrm{g}}{ }^0, \mathrm{~d}^2 \mathrm{sp}^3\), Low spin ( 3 d series +SFL ) (B)…
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- Which among the following react with Hinsberg's reagent?

Choose the correct answer from the options given below:JEE Mains 2025 Easy - Given below are two statements :
Statement (I): Experimentally determined oxygen-oxygen bond lengths in the \(\mathrm{O}_3\) are found to be same and the bond length is greater than that of a \(\mathrm{O}=\mathrm{O}\) (double bond) but less than that of a single \((O-O)\) bond.
Statement (II) : The strong lone pair-lone pair repulsion between oxygen atoms is solely responsible for the fact that the bond length in ozone is smaller than that of a double bond \((\mathrm{O}=\mathrm{O})\) but more than that of a single bond \((\mathrm{O}-\mathrm{O})\).
In the light of the above statements, choose the correct answer from the options given below :JEE Mains 2025 Medium - The decreasing order of basicity of the following amines is
JEE Mains 2020 Medium - Match the LIST-I with LIST-II
List-I
Electronic configuration of tetrahedral metal ionList-II
Crystal Field Stabilization Energy (\(\Delta_t\))A. \(d^2\) I. \(-0.6\) B. \(d^4\) II. \(-0.8\) C. \(d^6\) III. \(-1.2\) D. \(d^8\) IV. \(-0.4\)
Choose the correct answer from the options given below:JEE Mains 2026 Hard - Identify the correct statement for \(B _{2} H _{6}\) from those given below. \((A)\) In \(B _{2} H _{6}\), all \(B - H\) bonds are equivalent. \((B)\) In \(B _{2} H _{6}\) there are four \(3-\)centre\(-2-\)electron bonds. \((C)\) \(B _{2} H _{6}\) is a Lewis acid. \((D)\) \(B _{2} H _{6}\) can be synthesized form both \(BF _{3}\) and \(NaBH _{4}\). \((E)\) \(B _{2} H _{6}\) is a planar molecule. Choose the most appropriate answer from the options given below..... .JEE Mains 2022 Easy
- The Total pressure observed by mixing two liquid \(A\) and \(B\) is \(350\,mm\,Hg\) when their mole fractions are \(0.7\) and \(0.3\) respectively.The Total pressure becomes \(410 \,mm\,Hg\) if the mole fractions are changed to \(0.2\) and \(0.8\) respectively for \(A\) and \(B\). The vapour pressure of pure \(A\) is \(...........\,mm\,Hg\). (Nearest integer) Consider the liquids and solutions behave ideally.JEE Mains 2023 Medium
More PYQs from JEE Mains
- In the potentiometer, when the cell in the secondary circuit is shunted with 4 \(\Omega\) resistance, the balance is obtained at the length 120 cm of wire. Now when the same cell is shunted with 12 \(\Omega\) resistance, the balance is shifted to a length of 180 cm. The internal resistance of cell is ___________ \(\Omega\).JEE Mains 2026 Medium
- Let a plane \(P\) pass through the point \((3,7,-7)\) and contain the line, \(\frac{x-2}{-3}=\frac{y-3}{2}=\frac{z+2}{1} .\) If distance of the plane \(P\) from the origin is \(d\), then \(d^{2}\) is equal to \(.....\)JEE Mains 2021 Medium
- In an experiment to determine the Young's modulus, steel wires of five different lengths \((1,2,3,4\) and \(5\,m )\) but of same cross section \(\left(2\,mm ^{2}\right)\) were taken and curves between extension and load were obtained. The slope (extension/load) of the curves were plotted with the wire length and the following graph is obtained. If the Young's modulus of given steel wires is \(x \times 10^{11}\,Nm ^{-2}\), then the value of \(x\) is
JEE Mains 2022 Hard - The charge accumulated on the capacitor connected in the following circuit is________ \(\mu \mathrm{C}\) (Given \(\mathrm{C}=150\ \mu \mathrm{F}\))
JEE Mains 2024 Hard - Identify the correct order for the given property for following compounds.Choose the correct answer from the option given below :-
JEE Mains 2023 Medium - Consider the following \(Zn^{2+} + 2e^-\) \(\longrightarrow\) \(Zn (s) ; E^o = -0.76\,V\) \(Ca^{2+} + 2e^-\) \(\longrightarrow\) \(Ca (s) ; E^o = -2.87\,V\) \(Mg^{2+} + 2e^-\) \(\longrightarrow\) \(Mg (s) ; E^o = -2.36\,V\) \(Ni^{2+} + 2e^-\) \(\longrightarrow\) \(Ni (s) ; E^o = -0.25\,V\) The reducing power of the metals increases in the orderJEE Mains 2019 Hard