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JEE Mains · Chemistry · STD 12 -1. Solution and colligative properties

A solution of two miscible liquids showing negative deviation from Raoult's law will have :

  1. A increased vapour pressure, increased boiling point
  2. B increased vapour pressure, decreased boiling point
  3. C decreased vapour pressure, decreased boiling point
  4. D decreased vapour pressure, increased boiling point
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Answer & Solution

Correct Answer

(D) decreased vapour pressure, increased boiling point

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Detailed explanation

Solution with negative deviation has \( \mathrm{P}_{\mathrm{T}}<\mathrm{P}_{\mathrm{A}^0} \mathrm{X}_{\mathrm{A}} +\mathrm{P}_{\mathrm{B}^0} \mathrm{X}_{\mathrm{B}} \) \( \mathrm{P}_{\mathrm{A}}<\mathrm{P}_{\mathrm{A}^0} \mathrm{X}_{\mathrm{A}} \)…
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