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JEE Mains · Chemistry · STD 12 - 7. Alcohol, phenol and ethers

Given below are two statements : One is labelled as Assertion \(A\) and the other is labelled as Reason \(R\). Assertion \(A\): \(\mathrm{pK}_{\mathrm{a}}\) value of phenol is \(10.0\) while that of ethanol is \(15.9\). Reason \(R\): Ethanol is stronger acid than phenol.In the light of the above statements. choose the correct answer from the options given below:

  1. A \(A\) is true but \(R\) is false.
  2. B A is false but \(R\) is true.
  3. C Both \(A\) and \(R\) are true and \(R\) is the correct explanation of \(A\).
  4. D Both \(A\) and \(R\) are true but \(R\) is NOT the correct explanation of \(A\).
Verified Solution

Answer & Solution

Correct Answer

(A) \(A\) is true but \(R\) is false.

Step-by-step Solution

Detailed explanation

Phenol is more acidic than ethanol because conjugate base of phenoxide is more stable than ethoxide.