JEE Mains · Chemistry · STD 11 - 6.1. Equilibrium - 1 (chemical Equilibrium)
Consider the following equilibrium, \(\mathrm{CO}(\mathrm{g})+2 \mathrm{H}_2(\mathrm{g}) \rightleftharpoons \mathrm{CH}_3 \mathrm{OH}(\mathrm{g})\) 0.1 mol of CO along with a catalyst is present in a \(2 \mathrm{dm}^3\) flask maintained at 500 K. Hydrogen is introduced into the flask until the pressure is 5 bar and 0.04 mol of \(\mathrm{CH}_3 \mathrm{OH}\) is formed. The \(\mathrm{K}_{\mathrm{p}}^0\) is ______ \(\times 10^{-3}\) (nearest integer).
Given : \(\mathrm{R}=0.08 \mathrm{dm}^3\) bar \(\mathrm{K}^{-1} \mathrm{~mol}^{-1}\)
Assume only methanol is formed as the product and the system follows ideal gas behaviour.
- A 70
- B 74
- C 76
- D 78
Answer & Solution
Correct Answer
(B) 74
Step-by-step Solution
Detailed explanation
\begin{array}{llll} & \mathrm{CO}(\mathrm{g}) & + & 2 \mathrm{H}_2(\mathrm{g}) & \rightleftharpoons & \mathrm{CH}_3 \mathrm{OH}(\mathrm{g}) \\ \mathrm{t}=0 & 0.1 \mathrm{~mol} & & \mathrm{a} \mathrm{~mol} & & - \\ \mathrm{t}_{\text {eq }} & 0.1-\mathrm{x} & & \mathrm{a}-2…
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