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JEE Mains · Chemistry · STD 11 - 4. Chemical bonding and molecular structure

Among the following molecules / ions \(C_2^{2-} ,N_2^{2-} ,O_2^{2-},O_2\) which one is diamagnetic and has the shortest bond length ?

  1. A \(O_2^{2-}\)
  2. B \(C_2^{2-}\)
  3. C \(O_2\)
  4. D \(N_2^{2-}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(C_2^{2-}\)

Step-by-step Solution

Detailed explanation

\(C_2^{2 - } - {\sigma _{1s}}2{\sigma ^*}_{1s}2{\sigma _{2s}}2{\sigma ^*}_{2{s^2}}[{\pi _{2p_x^2}} = {\pi _2}p_y^2]{\sigma _{2p_z^2}}\) \(B.O = \frac{{10 - 4}}{2} = 3\) (diamagnetic)…
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