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JEE Advanced · Physics · 27. Atomic Physics

Paragraph:
The key feature of Bohr's theory of spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid. The rule to be applied is Bohr's quantization condition.
Question:
A diatomic molecule has moment of inertia I. By Bohr's quantization condition its rotational energy in the \(n\)th level ( \(n=0\) is not allowed) is

  1. A \(\frac{1}{n^2}\left(\frac{h^2}{8 \pi^2 I}\right)\)
  2. B \(\frac{1}{n}\left(\frac{h^2}{8 \pi^2 I}\right)\)
  3. C \(n\left(\frac{h^2}{8 \pi^2 I}\right)\)
  4. D \(n^2\left(\frac{h^2}{8 \pi^2 I}\right)\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(n^2\left(\frac{h^2}{8 \pi^2 I}\right)\)

Step-by-step Solution

Detailed explanation

\(
\begin{aligned}
L=I \omega & =\frac{n h}{2 \pi} \therefore \omega=\frac{n h}{2 \pi I} \\
K & =\frac{1}{2} I \omega^2=\frac{1}{2} I\left(\frac{n h}{2 \pi I}\right)^2 \\
& =\frac{n^2 h^2}{8 \pi^2 I}
\end{aligned}
\)
\(\therefore\) The correct answer is (d).
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