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JEE Advanced · Chemistry · 31. Practical Chemistry

Which of the following halides react(s) with \(\mathrm{AgNO}_{3}(\mathrm{aq})\) to give a precipitate that dissolves in \(\mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3}(\mathrm{aq})\) ?

  1. A \(\mathrm{HCl}\)
  2. B \(\mathrm{HF}\)
  3. C \(\mathrm{HBr}\)
  4. D \(\mathrm{HI}\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(\mathrm{HCl}\)

Step-by-step Solution

Detailed explanation

\(\mathrm{HX}+\mathrm{AgNO}_{3} \longrightarrow \mathrm{AgX} \downarrow+\mathrm{HNO}_{3}(\mathrm{X}=\) \(\mathrm{Cl}, \mathrm{Br}, \mathrm{I}) \)
\( \mathrm{AgX}+2 \mathrm{Na}_{2} \mathrm{~S}_{2} \mathrm{O}_{3} \longrightarrow \mathrm{Na}_{3}\left[\mathrm{Ag}\left(\mathrm{S}_{2} \mathrm{O}_{3}\right)_{2}\right]+\) \(\mathrm{NaX}\)
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