When the following aldohexose exists in its D-configuration, the total number of stereoisomers in its pyranose form is :
\(\mathrm{CHO}-\mathrm{CH}_{2}-\mathrm{CHOH}-\mathrm{CHOH}-\mathrm{CHOH}\) \(-~\mathrm{CH}_{2} \mathrm{OH}\)

Reaction of \(\mathbf{x}\) g of \(\mathrm{Sn}\) with \(\mathrm{HCl}\) quantitatively produced a salt. Entire amount of the salt reacted with \(\mathbf{y} g\) of nitrobenzene in the presence of required amount of \(\mathrm{HCl}\) to produce \(1.29 \mathrm{~g}\) of an organic salt (quantitatively).
(Use Molar masses (in \(\mathrm{g} \mathrm{mol}^{-1}\) ) of \(\mathrm{H}, \mathrm{C}, \mathrm{N}, \mathrm{O}, \mathrm{Cl}\) and \(\mathrm{Sn}\) as \(1,12,14,16,35\) and 119 , respectively).
The value of $\mathrm{y}$ is_________ .

Mixture(s) showing positive deviation from Raoult's law at ${35}^{\mathrm{o}}\mathrm{C}$ is (are)

Solubility product constant \(\left(K_{\mathrm{sp}}\right)\) of salts of types \(M X, M X_2\) and \(M_3 X\) at temperature ' \(T\) ' are \(4.0 \times 10^{-8}, 3.2 \times 10^{-14}\) and \(2.7 \times 10^{-15}\), respectively. Solubilities \(\left(\mathrm{mol} \mathrm{dm}^{-3}\right)\) of the salts at temperature ' \(T\) ' are in the order

A gas has a compressibility factor of $0.5$ and a molar volume of $0.4 {\mathrm{dm}}^3 {\mathrm{mol}}^{-1}$ at a temperature of $800 \mathrm{K}$ and pressure $\mathrm{x} \mathrm{atm}$. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be  $\mathrm{y} {\mathrm{dm}}^3 {\mathrm{mol}}^{-1}$ . The value of$\mathrm{x}/\mathrm{y}$ is _________
[Use: Gas constant, $\mathrm{R}=8\times {10}^{-2} \mathrm{L} \mathrm{atm} {\mathrm{K}}^{-1} {\mathrm{mol}}^{-1}$ ]

The electrochemical cell shown below is a concentration cell. \(\mathrm{M} \mid \mathrm{M}^{2+}\) (saturated solution of a sparingly soluble salt, \(\left.\mathrm{MX}_{2}\right) \| \mathrm{M}^{2 \perp}\left(0.001 \mathrm{~mol} \mathrm{dm}^{-3}\right) \mid \mathrm{M}\).
The emf of the cell depends on the difference in concentrations of \(\mathrm{M}^{2+}\) ions at the two electrodes. The emf of the cell at \(298 \mathrm{~K}\) is \(0.059 \mathrm{~V}\).
Question:
The solubility product \(\left(\mathrm{K}_{s p} ; \mathrm{mol}^{3} \mathrm{dm}^{-9}\right)\) of \(\mathrm{MX}_{2}\) at \(298 \mathrm{~K}\) based on the information available for the given concentration cell is (take \(2.303 \times \mathrm{R} \times 298 / \mathrm{F}=0.059 \mathrm{~V}\) )

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\(RCONH _2\) is converted into \(RNH _2\) by means of Hofmann bromamide degradation.

In this reaction, \(R \mathrm{CONHBr}\) is formed from which this reaction has derived its name. Electron donating group at phenyl activates the reaction. Hofmann degradation reaction is an intramolecular reaction.
Question:
How can the conversion of (i) to (ii) be brought about?

Match the compounds in LIST-$\mathrm{I}$ with the observations in LIST-$\mathrm{II}$, and choose the correct option.

	LIST-$\mathrm{I}$		LIST-$\mathrm{II}$
$\left(\mathrm{I}\right)$	Aniline	$\left(\mathrm{P}\right)$	Sodium fusion extract of the compound on boiling with ${\mathrm{FeSO}}_4$, followed by acidification with conc. ${\mathrm{H}}_2{\mathrm{SO}}_4$, gives Prussian blue color.
$\left(\mathrm{II}\right)$	$\mathrm{o}-$Cresol	$\left(\mathrm{Q}\right)$	Sodium fusion extract of the compound on treatment with sodium nitroprusside gives blood red color.
$\left(\mathrm{III}\right)$	Cysteine	$\left(\mathrm{R}\right)$	Addition of the compound to a saturated solution of ${\mathrm{NaHCO}}_3$ results in effervescence.
$\left(\mathrm{IV}\right)$	Caprolactam	$\left(\mathrm{S}\right)$	The compound reacts with bromine water to give a white precipitate.
		$\left(\mathrm{T}\right)$	Treating the compound with neutral ${\mathrm{FeCl}}_3$ solution produces violet color.

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Consider the polynomial \(f(x)=1+2 x+3 x^2+4 x^3\). Let \(s\) be the sum of all distinct real roots of \(f(x)\) and let \(t=|s|\).Question:
The area bounded by the curve \(y=f(x)\) and the lines \(x=0, y=0\) and \(x=t\), lies in the interval

A parallel beam of light is incident from air at an angle $\alpha$ on the side PQ of a right angled triangular prism of refractive index $n=\sqrt{2}$ . Light undergoes total internal reflection in the prism at the face PR when $\alpha$ has a minimum value of ${45}^o.$ The angle $\theta$ of the prism is:

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Modern trains are based on Maglev technology in which trains are magnetically leviated, which runs its EDS Maglev system.
There are coils on both sides of wheels. Due to motion of train, current induces in the coil of track which levitate it. This is in accordance with Lenz's law. If trains lower down then due to Lenz's law a repulsive force increases due to which train gets uplifted and if it goes much high then there is a net downward force disc to gravity. The advantage of Maglev train is that there is no friction between the train and the track, thereby reducing power consumption and enabling the train to attain very high speeds.
Disadvantage of Maglev train is that as it slows down the electromagnetic forces decreases and it becomes difficult to keep it leviated and as it moves forward according to Lenz law, there is an electromagnetic drag force.
Question:
What is the advantage of this system?

An optical component and an object \(S\) placed along its optic axis are given in Column I. The distance between the object and the component can be varied. The properties of images are given in Column II. Match all the properties of images from Column II with the appropriate components given in Column I. Indicate your answer by darkening the appropriate bubble of the \(4 \times 4\) matrix given in the ORS.

A solid sphere is in pure rolling motion on an inclined surface having inclination \(\theta\).