Paragraph:
\(RCONH _2\) is converted into \(RNH _2\) by means of Hofmann bromamide degradation.

In this reaction, \(R \mathrm{CONHBr}\) is formed from which this reaction has derived its name. Electron donating group at phenyl activates the reaction. Hofmann degradation reaction is an intramolecular reaction.
Question:
How can the conversion of (i) to (ii) be brought about?

The IUPAC name of \(\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_4\right]\left[\mathrm{NiCl}_4\right]\) is

Match the compounds in List-I with the appropriate observations in List-II and choose the correct option.

List - I	List - II
(P)	(1) Reaction with phenyl diazonium salt gives #ff0 dye.
(Q)	(2) Reaction with ninhydrin gives purple color and it also reacts with \(FeCl _3\) to give violet color.
(R)	(3) Reaction with glucose will give corresponding hydrazone.
(S)	(4) Lassiagne extract of the compound treated with dilute HCl followed by addition of aqueous \(FeCl _3\) gives blood red color.
	(5) After complete hydrolysis,it will give ninhydrin test and it DOES NOT give positive phthalein dye test.

For the electrochemical cell, $\text{Mg(s)}\left|{\text{Mg}}^{\text{2+}}\left(\text{aq,1}\text{M}\right)\right|\left|{\text{Cu}}^{\text{2+}}\left(\text{aq,1}\text{M}\right)\right|\text{Cu }\left(\text{s}\right)$ the standard emf of the cell is $\text{2}\text{.70 V}$ at $\text{300 K}\text{.}$ When the concentration of ${\text{Mg}}^{\text{2+}}$ is changed to $\text{x M,}$ the cell potential changes to $\text{2}\text{.67 V}$ at $\text{300 K}\text{.}$ The value of $\text{x}$ is ________.
(given, $\frac{\text{F}}{\text{R}}{\text{=11500 K V}}^{-\text{1}}\text{,}$ where $\text{F}$ is the Faraday constant and $\text{R}$ is the gas constants, $\text{ln}\left(\text{10}\right)\text{=}\text{2}\text{.30}$ )

The colour of light absorbed by an aqueous solution of \(\mathrm{CuSO}_{4}\) is:

Among \(\mathrm{V}(\mathrm{CO})_6, \mathrm{Cr}(\mathrm{CO})_5, \mathrm{Cu}(\mathrm{CO})_3,\)\(\operatorname{Mn}(\mathrm{CO})_5, \mathrm{Fe}(\mathrm{CO})_5,\left[\mathrm{Co}(\mathrm{CO})_3\right]^{3-},\left[\mathrm{Cr}(\mathrm{CO})_4\right]^{4-}\), and \(\operatorname{Ir}(\mathrm{CO})_3\), the total number of species isoelectronic with \(\mathrm{Ni}(\mathrm{CO})_4\) is ________.
[Given, atomic number:\(\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Mn}=25,\) \(\mathrm{Fe}=26, \mathrm{Co}=27, \mathrm{Ni}=28, \mathrm{Cu}=29,\) \(\mathrm{Ir}=77\)]

The green colour produced in the borax bead test of a chromium(III) salt is due to -

Paragraph:
If a continuous \(f\) defined on the real line \(R\), assume positive and negative values in \(R\), then the equation \(f(x)=0\) has a root in \(R\). For example, if it is known that a continuous function \(f\) on \(R\) is positive at some point and its minimum values is negative, then the equation \(f(x)=0\) has a root in \(R\).
Consider \(f(x)=k e^x-x\) for all real \(x\), where \(k\) is real constant.Question:
The line \(y=x\) meets \(y=k e^x\) for \(k \leq 0\) at

Paragraph :

A thermal power plant produces electric power of \(600 \mathrm{~kW}\) at \(4000 \mathrm{~V}\), which is to be transported to a place \(20 \mathrm{~km}\) away from the power plant for consumers' usage. It can be transported either directly with a cable of large current carrying capacity or by using a combination of step-up and step-down transformers at the two ends. The drawback of the direct transmission is the large energy dissipation. In the method using transformers, the dissipation is much smaller. In this method, a step-up transformer is used at the plant side so that the current is reduced to a smaller value. At the consumers' end, a step-down transformer is used to supply power to the consumers at the specified lower voltage. It is reasonable to assume that the power cable is purely resistive and the transformers are ideal with a power factor unity. All the currents and voltages mentioned are rms values.

Question :

In the method using the transformers, assume that the ratio of the number of turns in the primary to that in the secondary in the step-up transformer is \(1: 10\). If the power to the consumers has to be supplied at \(200 \mathrm{~V}\), the ratio of the number of turns in the primary to that in the secondary in the step-down transformer is

Internal bisector of \(\angle A\) of \(\triangle A B C\) meets side \(B C\) at \(D\). A line drawn through \(D\) perpendicular to \(A D\) intersects the side \(A C\) at \(E\) and side \(A B\) at \(F\). If \(a, b\) and \(c\) represent sides of \(\triangle A B C\), then

A block with mass M is connected by a massless spring with stiffness constant k to a rigid wall and moves without friction on a horizontal surface. The block oscillates with small amplitude A about an equilibrium position $x_0$. Consider two cases : (i) when the block is at $x_0\text{;}$ and (ii) when the block is at $x=x_0+\text{A}\text{.}$ In both the cases, a particle with mass m $\left(<\text{M}\right)$ is softly placed on the block after which they stick to each other. Which of the following statement(s) is(are) true about the motion after the mass m is placed on the mass M?

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match each entry in List-I with the appropriate entry in List-II and choose the correct options.

List - I	List - II
(P) Stephen reaction	(1)
(Q) Sandmeyer reaction	(2)
(R) Hoffmann bromamide degradation reaction	(3)
(S) Cannizzaro reaction	(4)
	(5)

Paragraph :
A wooden cylinder of diameter \(4 r\), height \(H\) and density \(\rho / 3\) is kept on a hole of diameter \(2 r\) of a tank, filled with liquid of density \(\rho\) as shown in the figure.

Question :
Now level of the liquid starts decreasing slowly. When the level of liquid is at a height \(h_1\) above the cylinder, the block starts moving up. At what value of \(h_1\), will the block rise?