The nitrogen oxide(s) that contain(s) N.N bond(s) is (are)

For an ideal gas, consider only P-V work in going from an initial state \(\mathrm{X}\) to the final state \(\mathrm{Z}\). The final state \(\mathrm{Z}\) can be reached by either of the two paths shown in the figure. Which of the following choice(s) is (are) correct?
[Take \(\Delta \mathrm{S}\) as change in entropy and w as work done].

One mole of an ideal gas at $300 \mathrm{K}$ in thermal contact with its surroundings expands isothermally from $1.0 \mathrm{L}$ to $2.0 \mathrm{L}$ against a constant pressure of $3.0 \mathrm{atm}$. In this process, the change in entropy of the surroundings $\left(∆{\mathrm{S}}_{\mathrm{s}\mathrm{u}\mathrm{r}\mathrm{r}}\right)$ in $\mathrm{J}\mathrm{ }{\mathrm{K}}^{-1}$ is:
$\left(1 \mathrm{L} \mathrm{atm} = 101.3 \mathrm{J}\right)$

Match the reactions (in the given stoichiometry of the reactants) in List-I with one of their products given in List-II and choose the correct option.

List - I	List - II
(P) \(P _2 O _3\) \(+~3 H _2 O \rightarrow\)	(1) \(P ( O )\left( OCH _3\right)\) \(Cl _2\)
(Q) \(P _4+3 NaOH\) \(+~3 H _2 O \rightarrow\)	(2) \(H _3 PO _3\)
(R) \(PCl _5+ CH _3\) \(COOH \rightarrow\)	(3) \(PH _3\)
(S) \(H _3 PO _2\) \(+~2 H _2 O ~+\) \(4 AgNO _3 \rightarrow\)	(4) \(POCL _3\)
	(5) \(H _3 PO _4\)

To an evacuated vessel with movable piston under external pressure of \(1 \mathrm{~atm}\), \(0.1\) mole of He and \(1.0\) mole of an unknown compound (vapour pressure \(0.68 mathrm{~atm}\) at \(0^{\circ} \mathrm{C}\) ) are introduced. Considering the ideal gas behaviour, the total volume (in litre) of the gases at \(0^{\circ} \mathrm{C}\) is close to

The correct statement(s) about of the following reaction sequence is(are)

Among the following complexes, the total number of diamagnetic species is_____
\(\left[\mathrm{Mn}\left(\mathrm{NH}_3\right)_6\right]^{3+},\left[\mathrm{MnCl}_6\right]^{3-},\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{CoF}_6\right]^{3-},\)\(\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{3+}\), and \(\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}\)
[Given, atomic number: \(\mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27\);
\(\text { en } \left.=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2\right]\)

For any real numbers $\alpha$ and $\beta$, let $y_{\alpha ,\beta }\left(x\right),x\in R$, be the solution of the differential equation $\frac{dy}{dx}+\alpha y=x{e}^{\beta x},y\left(1\right)=1$ Let $S=\left\{y_{\alpha ,\beta }\left(x\right) :\alpha ,\beta \in R\right\}$. Then which of the following functions belong(s) to the set $S$?

Let $S$ be the reflection of a point $Q$ with respect to the plane given by
$\overrightarrow{r}=-\left(t+p\right)\hat{i}+t\hat{j}+\left(1+p\right)\hat{k}$
where $t,p$ are real parameters and $\hat{i},\hat{j},\hat{k}$ are the unit vectors along the three positive coordinate axes. If the position vectors of $Q$ and $S$ are $10\hat{i}+15\hat{j}+20\hat{k}$ and $\alpha \hat{i}+\beta \hat{j}+\gamma \hat{k}$ respectively, then which of the following is/are TRUE?

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\(\mathbf{X}\) and \(\mathbf{Y}\) are two volatile liquids with molar weights of \(10 \mathrm{~g} \mathrm{~mol}^{-1}\) and \(40 \mathrm{~g} \mathrm{~mol}^{-1}\) respectively. Two cotton plugs, one soaked in \(\mathbf{X}\) and the other soaked in \(\mathbf{Y}\), are simultaneously placed at the ends of a tube of length \(L=24 \mathrm{~cm}\), as shown in the figure. The tube is filled with an inert gas at \(1\) atmosphere pressure and a temperature of \(300 \mathrm{~K}\). Vapours of \(\mathbf{X}\) and \(\mathbf{Y}\) react to form a product which is first observed at a distance \(\mathbf{d} \mathrm{~cm}\) from the plug soaked in \(\mathbf{X}\). Take \(\mathbf{X}\) and \(\mathbf{Y}\) to have equal molecular diameters and assume ideal behaviour for the inert gas and the two vapours.



Question:

The value of \(\mathbf{d}\) in \(\mathbf{c m}\) (shown in the figure), as estimated from Graham's law, is

Let \(f(x)=2+\cos x\) for all real \(x\).
Statement I For each real \(t\), there exists a point \(c\) in \([t, t+\pi]\) such that \(f^{\prime}(c)=0\).
Statement II \(f(t)=f(t+2 \pi)\) for each real \(t\).

A projectile is thrown from a point \(\mathrm{O}\) on the ground at an angle \(45^{\circ}\) from the vertical and with a speed \(5 \sqrt{2} \mathrm{~m} / \mathrm{s}\). The projectile at the highest point of its trajectory splits into two equal parts. One part falls vertically down to the ground, \(0.5 \mathrm{~s}\) after the splitting. The other part, \(t\) seconds after the splitting, falls to the ground at a distance \(x\) meters from the point O. The acceleration due to gravity \(g=10 \mathrm{~m} / \mathrm{s}^{2}\).
The value of $t$ is _________.

A plane polarized blue light ray is incident on a prism such that there is no reflection from the surface of the prism. The angle of deviation of the emergent ray is $\delta ={60}^{\mathrm{o}}$ (see Figure-$1$). The angle of minimum deviation for red light from the same prism is ${\delta }_{\min }={30}^{\mathrm{o}}$ (see Figure-$2$). The refractive index of the prism material for blue light is $\sqrt{3}$. Which of the following statement(s) is(are) correct?