Match the reactions (in the given stoichiometry of the reactants) in List-I with one of their products given in List-II and choose the correct option.

List - I	List - II
(P) \(P _2 O _3\) \(+~3 H _2 O \rightarrow\)	(1) \(P ( O )\left( OCH _3\right)\) \(Cl _2\)
(Q) \(P _4+3 NaOH\) \(+~3 H _2 O \rightarrow\)	(2) \(H _3 PO _3\)
(R) \(PCl _5+ CH _3\) \(COOH \rightarrow\)	(3) \(PH _3\)
(S) \(H _3 PO _2\) \(+~2 H _2 O ~+\) \(4 AgNO _3 \rightarrow\)	(4) \(POCL _3\)
	(5) \(H _3 PO _4\)

The equilibrium \(2 \mathrm{Cu}^{\mathrm{I}} \rightleftharpoons \mathrm{Cu}^0+\mathrm{Cu}^{\text {II }}\) in aqueous medium at \(25^{\circ} \mathrm{C}\) shifts towards the left in the presence of

The order of the oxidation state of the phosphorus atom in $H_{3}P{O}_2, H_{3}P{O}_4, H_{3}P{O}_3$ and $H_4{P}_2{O}_6$ is

For the reaction sequence given below, the correct statement(s) is(are)

Paragraph:
Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The freezing point of the solution \(M\) is

Paragraph:
An acylic hydrocarbon \(P\), having molecular formula \(\mathrm{C}_6 \mathrm{H}_{10}\), gave acetone as the only organic product through the following sequence of reactions, in which \(Q\) is an intermediate organic compounds.

Question:
The structure of compound P is

Paragraph:
The concentration of potassium ions inside a biological cell is at least twenty times higher than the outside. The resulting potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining the ion balance. A simple model for such a concentration cell involving a metal \(\mathrm{M}\) is :
\(
M(s) \mid M^{+}(\alpha q ; 0.05 \text { molar }) \| M^{+}(a q ; 1 \text { molar })\) \(\mid M(s)
\)
For the above electrolytic cell the magnitude of the cell potential \(\left|E_{\text {cell }}\right|=70 \mathrm{mV}\).
Question:
If the \(0.05\) molar solution of \(M^{+}\)is replaced by a \(0.0025\) molar \(M^{+}\) solution, then the magnitude of the cell potential would be

Hydrogen bonding plays a central role in the following phenomena:

Consider an obtuse angled triangle $ABC$ in which the difference between the largest and the smallest angle is $\frac{\pi }{2}$ and whose sides are in arithmetic progression. Suppose that the vertices of this triangle lie on a circle of radius $1$.

(There are two questions based on $\mathrm{PARAGRAPH} " 1 "$, the question given below is one of them)
Then the inradius of the triangle $ABC$ is

In allene \(\left(\mathrm{C}_{3} \mathrm{H}_{4}\right)\), the type(s) of hybridisation of the carbon atoms is (are):

A radioactive sample \(S_1\) having an activity of \(5 \mu \mathrm{Ci}\) has twice the number of nuclei as another sample \(S_2\) which has an activity of \(10 \mu \mathrm{Ci}\). The half lives of \(S_1\) and \(S_2\) can be

A normal with slope \(\frac{1}{\sqrt{6}}\) is drawn from the point \((0,-\alpha)\) to the parabola \(x^2=-4 a y\), where \(a>0\). Let \(L\) be the line passing through \((0,-\alpha)\) and parallel to the directrix of the parabola. Suppose that \(L\) intersects the parabola at two points \(A\) and \(B\). Let \(r\) denote the length of the latus rectum and \(s\) denote the square of the length of the line segment \(A B\). If \(r: s=1: 16\), then the value of 24ais ________.

The circular scale of a screw gauge has 50 divisions and pitch of \(0.5 \mathrm{~mm}\). Find the diameter of sphere. Main scale reading is 2 .