The dilution processes of different aqueous solutions with water are given in LIST-I. The effects of dilution of the solutions on $[H^{+}]$ are given in LIST-II.
(Note: The degree of dissociation $(α)$ of a weak acid and a weak base is $< < 1;$ the degree of hydrolysis of salt is $< < 1; [H^{+}]$ represents the concentration of $H^{+}$ ions)
List - I List - II
A) 10 mL of $0.1\text{ M NaOH} +20\text{ mL}$ of 0.1 M acetic acid diluted to 60 mL . P) The value of $\left[\text H ^{+}\right]$does not change on dilution.
B) 20 mL of $0.1\text{ M NaOH} +20\text{ mL}$ of 0.1 M acetic acid diluted to 80 mL . Q) The value of $\left[\text H ^{+}\right]$changes to half of its initial value on dilution.
C) 20 mL of $0.1\text{ M HCl} +20\text{ mL}$ of 0.1 M ammonia solution diluted to 80 mL . R) The value of $\left[\text H ^{+}\right]$changes to two times its initial value on dilution.
D) 10 mL saturated solution of $\text{Ni} (\text{OH})_2$ in equilibrium with excess of solid $\text{Ni} (\text{OH})_2$ is diluted to 20 mL (solid $\text{Ni} (\text{OH})_2$ is still present after dilution). S) The value of $\left[\text H ^{+}\right]$changes to $\sqrt{ }$ times its initial value on dilution.
T) The value of $\left[\text H ^{+}\right]$changes to $\sqrt{2}$ times its initial value on dilution.

Match each process given in LIST-I with one or more effect(s) in LIST-II. The correct option is

Question

The dilution processes of different aqueous solutions with water are given in LIST-I. The effects of dilution of the solutions on

[H^{+}]

are given in LIST-II.
(Note: The degree of dissociation

(α)

of a weak acid and a weak base is

< < 1;

the degree of hydrolysis of salt is

< < 1; [H^{+}]

represents the concentration of

H^{+}

ions)

List - I	List - II
A) 10 mL of $0.1\text{ M NaOH} +20\text{ mL}$ of 0.1 M acetic acid diluted to 60 mL .	P) The value of $\left[\text H ^{+}\right]$does not change on dilution.
B) 20 mL of $0.1\text{ M NaOH} +20\text{ mL}$ of 0.1 M acetic acid diluted to 80 mL .	Q) The value of $\left[\text H ^{+}\right]$changes to half of its initial value on dilution.
C) 20 mL of $0.1\text{ M HCl} +20\text{ mL}$ of 0.1 M ammonia solution diluted to 80 mL .	R) The value of $\left[\text H ^{+}\right]$changes to two times its initial value on dilution.
D) 10 mL saturated solution of $\text{Ni} (\text{OH})_2$ in equilibrium with excess of solid $\text{Ni} (\text{OH})_2$ is diluted to 20 mL (solid $\text{Ni} (\text{OH})_2$ is still present after dilution).	S) The value of $\left[\text H ^{+}\right]$changes to $\sqrt{ }$ times its initial value on dilution.
	T) The value of $\left[\text H ^{+}\right]$changes to $\sqrt{2}$ times its initial value on dilution.

Match each process given in LIST-I with one or more effect(s) in LIST-II. The correct option is

Accepted Answer

(B) a-p;b-t;c-s;d-p;

Answer

(A) a-q;b-t;c-p;d-r;

Answer

(C) a-s;b-t;c-p;d-r;

Answer

(D) a-s;b-q;c-p;d-t;

List - I	List - II
A) 10 mL of \(0.1\text{ M NaOH} +20\text{ mL}\) of 0.1 M acetic acid diluted to 60 mL .	P) The value of \(\left[\text H ^{+}\right]\)does not change on dilution.
B) 20 mL of \(0.1\text{ M NaOH} +20\text{ mL}\) of 0.1 M acetic acid diluted to 80 mL .	Q) The value of \(\left[\text H ^{+}\right]\)changes to half of its initial value on dilution.
C) 20 mL of \(0.1\text{ M HCl} +20\text{ mL}\) of 0.1 M ammonia solution diluted to 80 mL .	R) The value of \(\left[\text H ^{+}\right]\)changes to two times its initial value on dilution.
D) 10 mL saturated solution of \(\text{Ni} (\text{OH})_2\) in equilibrium with excess of solid \(\text{Ni} (\text{OH})_2\) is diluted to 20 mL (solid \(\text{Ni} (\text{OH})_2\) is still present after dilution).	S) The value of \(\left[\text H ^{+}\right]\)changes to \(\sqrt{ }\) times its initial value on dilution.
	T) The value of \(\left[\text H ^{+}\right]\)changes to \(\sqrt{2}\) times its initial value on dilution.

Column I	Column II
(A) \(CH _3- CHBr - CD _3\) on treatment with alc. KOH gives \(CH _2= CH - CD _3\) as a major product.	(P) E1 reaction
(B) \(Ph - CHBr - CH _3\) reacts faster than \(Ph - CHBr - CD _3\)	(Q) E2 reaction
(C) \(Ph - CH _2- CH _2 Br\) on treatment with \(C _2 H _5 OD / C _2 H _5 O ^{-}\)gives \(Ph - CD = CH _2\) as the major product	(R) El cb reaction
(D) \(PhCH _2 CH _2 Br\) and \(PhCH _2 CH _2 Br\) react with same rate	(S) First order reaction

Answer & Solution