The atomic masses of $\mathrm{He}$ and $\mathrm{Ne}$ are $4$ and $20 \mathrm{amu}$, respectively. The value of the de Broglie wavelength of $\mathrm{He}$ gas at $-73° \mathrm{C}$ is "M" times that of the de Broglie wavelength of $\mathrm{Ne}$ at $727° \mathrm{C}$. M is:

The total number of lone pairs of electrons in ${\mathrm{N}}_2{\mathrm{O}}_3$ is

Extraction for zinc from zinc blende is achieved by

One mole of an ideal gas is taken from \(a\) to \(b\) along two paths denoted by the solid and the dashed lines as shown in the graph below. If the work done along the solid line path is \(W_s\) and that along the dotted line path is \(W_d\), then the integer closest to the ratio \(\frac{W_d}{W_s}\) is

In dilute aqueous ${\mathrm{H}}_2\mathrm{S}{\mathrm{O}}_4$ , the complex diaquodioxalatoferrate (II) is oxidized by ${\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}$ . For this reaction, the ratio of the rate of change of $\left[{\mathrm{H}}^{+}\right]$ to the rate of change of $\left[{\mathrm{M}\mathrm{n}\mathrm{O}}_4^{-}\right]$ is

The molar conductivity of a solution of a weak acid HX (0.01 M) is 10 times smaller than the molar conductivity of a solution of a weak acid HY (0.10 M). If ${\mathrm{\lambda }}_{{\mathrm{X}}^{-}}^0\approx {\mathrm{\lambda }}_{{\mathrm{Y}}^{-}}^0$ , the difference in their $\mathrm{p}{\mathrm{K}}_{\mathrm{a}}$ values, $\mathrm{p}{\mathrm{K}}_{\mathrm{a}}\left(\mathrm{H}\mathrm{X}\right)-\mathrm{p}{\mathrm{K}}_{\mathrm{a}}\left(\mathrm{H}\mathrm{Y}\right)$ , is (Consider degree of ionization of both acids to << 1)

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Chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules (approximately \(6.023 \times 10^{23}\) ) are present in a few grams of any chemical compound varying with their atomic/molecular masses. To handle such large numbers conveniently, the mole concept was introduced. This concept has implications in diverse areas such as analytical chemistry, biochemistry, electrochemistry and radiochemistry. The following example illustrates a typical case, involving chemical/electrochemical reaction, which requires a clear understanding of the mole concept.
A \(4.0\) molar aqueous solution of \(\mathrm{NaCl}\) is prepared and \(500 \mathrm{~mL}\) of this solution is electrolysed. This leads to the evolution of chlorine gas at one of electrodes (atomic mass: \(\mathrm{Na}=23, \mathrm{Hg}=200 ; 1\) faraday \(=96500\) coulombs).
Question:
The total charge (coulombs) required for complete electrolysis is

The value of the integral $\underset{0}{\overset{\frac{1}{2}}{\int }}\frac{1+\sqrt{3}}{{\left({\left(x+1\right)}^2{\left(1-x\right)}^6\right)}^{\frac{1}{4}}} dx$ is

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Electrical resistance of certain materials, known as superconductors, changes abruptly from a non-zero value to zero as their temperature is lowered below a critical temperature \(T_C(0)\). An interesting property of superconductors is that their critical temperature becomes smaller than \(T_C(0)\) if they are placed in a magnetic field i.e., the critical temperature \(T_C(B)\) is a function of the magnetic field strength \(B\). The dependence of \(T_C(B)\) on \(B\) is shown in the figure.

Question :
A superconductor has \(T_C(0)=100 \mathrm{~K}\). When a magnetic field of \(7.5\) Tesla is applied, its \(T_C\) decreases to \(75 \mathrm{~K}\). For this material one can definitely say that when (Note : \(\mathrm{T}\) = Tesla)

In the figure, a ladder of mass m is shown leaning against a wall. It is in static equilibrium making an angle $\mathrm{\theta }$ with the horizontal floor. The coefficient of friction between the wall and the ladder is ${\mathrm{\mu }}_1$ and that between the floor and the ladder is ${\mathrm{\mu }}_2$ . The normal reaction of the wall on the ladder is ${\mathrm{N}}_1$ and that of the floor is ${\mathrm{N}}_2$ If the ladder is about to slip, then

A thin circular coin of mass $5 \mathrm{gm}$ and radius $\frac{4}{3} \mathrm{cm}$ is initially in a horizontal $xy$-plane. The coin is tossed vertically up ($+z$ direction) by applying an impulse of $\sqrt{\frac{\mathrm{\pi }}{2}}\times {10}^{-2} \mathrm{N}-\mathrm{s}$ at a distance $\frac{2}{3} \mathrm{cm}$ from its center. The coin spins about its diameter and moves along the $+z$ direction. By the time the coin reaches back to its initial position, it completes $n$ rotations. The value of $n$ is _____. [Given: The acceleration due to gravity $g=10 \mathrm{m} {\mathrm{s}}^{-2}$]

Consider the following linear equations
\[
a x+b y+c z=0, b x+c y+a z=0, c x+a y+b z=0
\]
Match the conditions/expressions in Column I with statements in Column II.

Let $\mathrm{M}=\left[\begin{array}{ccc}0& 1& \mathrm{a}\\ 1& 2& 3\\ 3& b& 1\end{array}\right]$ and $\mathrm{a}\mathrm{d}\mathrm{j}\mathrm{M}=\left[\begin{array}{ccc}-1& 1& -1\\ 8& -6& 2\\ -5& 3& -1\end{array}\right]$ where $\mathrm{a}$ and $\mathrm{b}$ are real numbers. Which of the following options is/are correct?