The ammonia is prepared by treating ammonium sulphate with calcium hydroxide is completely used by ${\mathrm{NiCl}}_2\mathbf{·}6{\mathrm{H}}_2\mathrm{O}$ to form a stable coordination compound. Assume that, both the reactions are $100\%$ completed. If $1584 \mathrm{g}$ of ammonium sulphate and $952 \mathrm{g}$ of ${\mathrm{NiCl}}_2\mathbf{·}6{\mathrm{H}}_2\mathrm{O}$ are used in the preparation, the combined weight (in grams) of gypsum and the nickel ammonia coordination compound produced is ____. Atomic weights in $\mathrm{g}\mathrm{ }{\mathrm{mol}}^{-1}$: $$\begin{gathered} \mathrm{H}=1;\mathrm{ }\mathrm{N}=14\mathrm{ } \\ \mathrm{O}=16; \mathrm{S}=32\mathrm{ } \\ \mathrm{Cl}=35.5;\mathrm{ }\mathrm{Ca}=40\mathrm{ } \\ \mathrm{Ni}=59 \end{gathered}$$

Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is

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Properties such as boiling point, freezing point and vapour pressure of a pure solvent change when solute molecules are added to get homogeneous solution. These are called colligative properties. Applications of colligative properties are very useful in day-to-day life. One of its examples is the use of ethylene glycol and water mixture as anti-freezing liquid in the radiator automobiles.
A solution \(M\) is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixtrue is \(0.9\)
Given Freezing point depression constant of water \(\left(k^{\text {water }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\)
Freezing point depression constant of ethanol \(\left(k_f^{\text {ethanol }}\right)=2.0 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of water \(\left(k_b^{\text {water }}\right)=0.52 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Boiling point elevation constant of ethanol \(\left(k_b^{\text {ethanol }}\right)=1.2 \mathrm{Kkg} \mathrm{mol}^{-1}\)
Standard freezing point of water \(=273 \mathrm{~K}\)
Standard freezing point of ethanol \(=155.7 \mathrm{~K}\)
Standard boiling point of water \(=373 \mathrm{~K}\)
Standard boiling point of ethanol \(=351.5 \mathrm{~K}\)
Vapour pressure of pure water \(=328 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Vapour pressure of pure ethanol \(=40 \mathrm{~mm}\) of \(\mathrm{Hg}\)
Molecular weight of water \(=18 \mathrm{~g} \mathrm{~mol}^{-1}\)
Molecular weight of ethanol \(=46 \mathrm{~g} \mathrm{~mol}^{-1}\)
In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and non-dissociative.

Question:
The vapour pressure of the solution \(M\) is

The structure of a peptide is given below.
If the absolute values of the net charge of the peptide at $\mathrm{pH}=2,\mathrm{pH}=6,$ and $\mathrm{pH}=11$ are $\left|{\mathrm{z}}_1\right|,\left|{\mathrm{z}}_2\right|,$ and $\left|{\mathrm{z}}_3\right|,$ respectively, then what is $\left|{\mathrm{z}}_1\right|+\left|{\mathrm{z}}_2\right|+\left|{\mathrm{z}}_3\right|$?

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Upon heating \(\mathrm{KClO}_{3}\) in the presence of catalytic amount of \(\mathrm{MnO}_{2}\), a gas \(\mathbf{W}\) is formed. Excess amount of \(\mathbf{W}\) reacts with white phosphorus to give \(\mathbf{X}\). The reaction of \(\mathbf{X}\) with pure \(\mathrm{HNO}_{3}\) gives \(\mathbf{Y}\) and \(\mathbf{Z}\).
Question:
\(\mathbf{Y}\) and \(\mathbf{Z}\) are, respectively

Vessel-1 contains \(\mathbf{w}_2 \mathrm{~g}\) of a non-volatile solute \(\mathbf{X}\) dissolved in \(\mathbf{w}_1 \mathrm{~g}\) of water. Vessel- 2 contains \(\mathbf{w}_2 \mathrm{~g}\) of another non-volatile solute \(\mathbf{Y}\) dissolved in \(\mathbf{w}_1 \mathrm{~g}\) of water. Both the vessels are at the same temperature and pressure. The molar mass of \(\mathbf{X}\) is \(80 \%\) of that of \(\mathbf{Y}\). The van't Hoff factor for \(\mathbf{X}\) is 1.2 times of that of \(\mathbf{Y}\) for their respective concentrations.
The elevation of boiling point for solution in Vessel-1 is ________. \(\%\) of the solution in Vessel-2.

Consider the strong electrolytes ${\mathrm{Z}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}, {\mathrm{U}}_{\mathrm{m}}{\mathrm{Y}}_{\mathrm{p}}$ and ${\mathrm{V}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}$. Limiting molar conductivity of ${\mathrm{U}}_{\mathrm{m}}{\mathrm{Y}}_{\mathrm{p}}$ and ${\mathrm{V}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}$ are $250$ and $440 \mathrm{S} {\mathrm{cm}}^2 {\mathrm{mol}}^{-1}$, respectively. The value of $\left(\mathrm{m}+\mathrm{n}+\mathrm{p}\right)$ is Given:

Ion	\(Z ^{ n +}\)	\(U ^{ p +}\)	\(V ^{ n +}\)	\(X ^{ m }\)	\(Y ^{ m -}\)
\(\lambda^0(\text{S cm} ^2\) \(\text{mol}^{-1})\)	50.0	25.0	100.0	80.0	100.0

${\lambda }^0$ is the limiting molar conductivity of ions The plot of molar conductivity $\left(\Lambda \right)$ of ${\mathrm{Z}}_{\mathrm{m}}{\mathrm{X}}_{\mathrm{n}}$ vs ${\mathrm{c}}^{\frac{1}{2}}$ is given below. If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.

A circuit is connected as shown in the figure with the switch \(S\) open. When the switch is closed, the total amount of charge that flows from \(Y\) to \(X\) is

The coefficient of $x^9$ in the expansion of $\left(1+x\right) \left(1+x^2\right) \left(1+x^3\right)\dots \dots \left(1+x^{100}\right)$ is

A uniform rod of length \(L\) and mass \(M\) is pivoted at the centre. Its two ends are attached to two springs of equal spring constants \(k\). The springs are fixed to rigid supports as shown in the figure, and rod is free to oscillate in the horizontal plane. The rod is gently pushed through a small angle \(\theta\) in one direction and released. The frequency of oscillation is

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A thermally insulating cylinder has a thermally insulating and frictionless movable partition in the middle, as shown in the figure below. On each side of the partition, there is one mole of an ideal gas, with specific heat at constant volume, \(C_{V}=2 R\). Here, \(R\) is the gas constant. Initially, each side has a volume \(V_{0}\) and temperature \(T_{0}\). The left side has an electric heater, which is turned on at very low power to transfer heat \(Q\) to the gas on the left side. As a result the partition moves slowly towards the right reducing the right side volume to \(V_{0} / 2\). Consequently, the gas temperatures on the left and the right sides become \(T_{L}\) and \(T_{R}\), respectively. Ignore the changes in the temperatures of the cylinder, heater and the partition.

Question :
The value of $\frac{T_R}{T_0}$ is:

Consider the region \(R=\left\{(x, y) \in \mathbb{R} \times \mathbb{R}: x \geq 0\right.\) and \(\left.y^{2} \leq 4-x\right\}\). Let \(\mathcal{F}\) be the family of all circles that are contained in \(R\) and have centers on the \(x\)-axis. Let \(C\) be the circle that has largest radius among the circles in \(\mathcal{F}\). Let \((\alpha, \beta)\) be a point where the circle \(C\) meets the curve \(y^{2}=4-x\).
The radius of the circles $C$ is____.

The center of a disk of radius \(r\) and mass \(m\) is attached to a spring of spring constant \(k\), inside a ring of radius \(R>r\) as shown in the figure. The other end of the spring is attached on the periphery of the ring. Both the ring and the disk are in the same vertical plane. The disk can only roll along the inside periphery of the ring, without slipping. The spring can only be stretched or compressed along the periphery of the ring, following the Hooke's law. In equilibrium, the disk is at the bottom of the ring. Assuming small displacement of the disc, the time period of oscillation of center of mass of the disk is written as \(T=\frac{2 \pi}{\omega}\). The correct expression for \(\omega\) is ( \(g\) is the acceleration due to gravity):