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Upon heating \(\mathrm{KClO}_{3}\) in the presence of catalytic amount of \(\mathrm{MnO}_{2}\), a gas \(\mathbf{W}\) is formed. Excess amount of \(\mathbf{W}\) reacts with white phosphorus to give \(\mathbf{X}\). The reaction of \(\mathbf{X}\) with pure \(\mathrm{HNO}_{3}\) gives \(\mathbf{Y}\) and \(\mathbf{Z}\).
Question:
\(\mathbf{Y}\) and \(\mathbf{Z}\) are, respectively

At room temperature, disproportionation of an aqueous solution of in situ generated nitrous acid \(\left(\mathrm{HNO}_2\right)\) gives the species

Which of the following statement(s) (are) correct regarding the root mean square speed $\left({\mathrm{U}}_{\mathrm{r}\mathrm{m}\mathrm{s}}\right)$ and average translational kinetic energy $\left({\mathrm{\epsilon }}_{\mathrm{a}\mathrm{v}}\right)$ of a molecule in a gas at equilibrium?

The Henry's law constant for the solubility of \(\mathrm{N}_2\) gas in water at \(298 \mathrm{~K}\) is \(1.0 \times 105 \mathrm{~atm}\). The mole fraction of \(\mathrm{N}_2\) in air is \(0.8\). The number of moles of \(\mathrm{N}_2\) from air dissolved in 10 moles of water of \(298 \mathrm{~K}\) and \(5 \mathrm{~atm}\) pressure is

The arrangement of X^- ions around A⁺ ion in solid AX is given in the figure (not drawn to scale). If the radius of X^- is 250 pm, the radius of A⁺ is

The maximum number of isomers (including stereoisomers) that are possible on monochlorination of the following compounds, is

The number of isomeric tetraenes (NOT containing sp-hybridized carbon atoms) that can be formed from the following reaction sequence is _____ .

Words of length$10$ are formed using the letters A, B, C, D, E, F, G, H, I, J. Let $x$ be the number of such words where no letter is repeated; and let $y$ be the number of such words where exactly one letter is repeated twice and no other letter is repeated. The, $\frac{y}{9x}=$

One mole of an ideal gas at $300 \mathrm{K}$ in thermal contact with its surroundings expands isothermally from $1.0 \mathrm{L}$ to $2.0 \mathrm{L}$ against a constant pressure of $3.0 \mathrm{atm}$. In this process, the change in entropy of the surroundings $\left(∆{\mathrm{S}}_{\mathrm{s}\mathrm{u}\mathrm{r}\mathrm{r}}\right)$ in $\mathrm{J}\mathrm{ }{\mathrm{K}}^{-1}$ is:
$\left(1 \mathrm{L} \mathrm{atm} = 101.3 \mathrm{J}\right)$

Let $m$ be the minimum possible value of ${\log }_3\left(3^{y_1}+3^{y_2}+3^{y_3}\right)$ , where $y_1, y_2, y_3$ are real numbers for which $y_1+y_2+y_3=9$. Let $M$ be the maximum possible value of $\left({\log }_3{x}_1+{\text{log}}_3 x_2+{\text{log}}_3 x_3\right)$, where $x_1, x_2, x_3$ are positive real numbers for which $x_1+x_2+x_3=9$. Then the value of ${\text{log}}_2 \left(m^3\right)+{\text{log}}_3\left(M^2\right)$ is

Using the data provided, calculate the multiple bond energy \(\left(\mathrm{kJ} \mathrm{mol}^{-1}\right)\) of a \(\mathrm{C} \equiv \mathrm{C}\) bond in \(\mathrm{C}_{2} \mathrm{H}_{2}\). That energy is (take the bond energy of a \(\mathrm{C}-\mathrm{H}\) bond as \(350 \mathrm{~kJ} \mathrm{~mol}^{-1}\) ) \(2 \mathrm{C}(\mathrm{s})+\mathrm{H}_{2}(\mathrm{~g}) \longrightarrow \mathrm{HC}=\mathrm{CH}(\mathrm{g}) ; \Delta \mathrm{H}=\) \(225 \mathrm{~kJ} \mathrm{~mol}^{-1}\) \(2 \mathrm{C}(\mathrm{s}) \longrightarrow 2 \mathrm{C}(\mathrm{g}) ; \Delta \mathrm{H}=1410 \mathrm{~kJ} \mathrm{~mol}^{-1}\) \(\mathrm{H}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{H}(\mathrm{g}) ; \Delta \mathrm{H}=330 \mathrm{~kJ} \mathrm{~mol}^{-1}\)

A number is chosen at random from the set $\left\{1,2,3,\dots ,2000\right\}$. Let $p$ be the probability that the chosen number is a multiple of 3 or $7$. Then the value of $500p$ is ____.

Among the following, the coloured compound is